[(N,N-di(2-picolyl)cyclohexylamine)Zn(NO₃)₂] | 1613729-07-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(N,N-di(2-picolyl)cyclohexylamine)Zn(NO₃)₂]
• 英文别名: [(dpca)Zn(NO₃)₂]
• CAS: 1613729-07-9
• 化学式: C₁₈H₂₃N₅O₆Zn
• 分子量: 470.801
• InChiKey: HPSIMFLMOHKAQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 N,N-di(2-picolyl)cyclohexylamine 以 乙醇 为溶剂， 反应 12.0h， 生成 [(N,N-di(2-picolyl)cyclohexylamine)Zn(NO₃)₂]
  参考文献：
  名称：

  Synthesis and structural characterization of [(dpca)MX2] (M=Cu, X=Cl; M=Cd, X=Br and M=Zn, X=NO3) complexes containing N,N-di(2-picolyl)cyclohexylamine (dpca) and their application to methyl methacrylate polymerization

  摘要：

  A novel series of [(dpca)MX2] (M = Cu, X = Cl; M = Cd, X = Br and M = Zn, X = NO3) complexes were synthesized through the reaction of N,N-di(2-picolyl)cyclohexylamine (dpca) with the corresponding metal starting materials. X-ray crystallographic analysis determined that the metal center in complexes [(dpca)CuCl2], [(dPca)CdBr2] and [(dpca)zn(NO3)(2)] showed a distorted 5-coordinated square pyramidal, trigonal bipyramidal, and 7-coordinated pentagonal bipyramidal geometry, respectively, involving coordination of the nitrogen atom of the cyclohexylamine moiety with the metal center. Specifically, the catalytic activity of [(dpca)Zn(NO3)(2)] (1.04 x 10(5)g PMMA/mol Zn.h) for the polymerization of methyl methacylate (MMA) in the presence of modified methylaluminoxane (MMAO) at 60 degrees C was six-fold higher than the reference complex [ZnCl2] (1.73 x 10(4) g PMMA/mol Zn.h). (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2014.04.005