| 10170-52-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• CAS: 10170-52-2
• 化学式: C₂₉H₄₄Co₂N₁₀O₈
• 分子量: 778.717
• InChiKey: BDHNZPCUQWGCTI-DQFUWSNMSA-J

反应信息

• 作为产物：
  描述：

  chloropyridinecobaloxime(III) 、 1,3-二溴丙烷 在 sodium tetrahydroborate 作用下， 以 not given 为溶剂， 以1%的产率得到(pyridine)((CH2)3Br)cobaloxime
  参考文献：
  名称：

  Organobridged dicobaloximes: Synthesis and NMR correlation

  摘要：

  Organobridged dicobaloximes of the type Py(L)(2)Co-III-(CH2)(n)-Co-III(L)(2)Py [L = dmgH(-) and dpgH(-), n = 3,4,5,6 and 10] are synthesized by the reaction of Co-l(L)(2)Py with the corresponding alkyl dihalides. A mixture of haloalkylcobaloximes and the dicobaloxime is formed in each reaction. The purification procedure for the dicobaloxime is established. A comparison of 'cis influence' due to the equatorial ligands in the haloalkyl and the dicobaloximes by H-1 NMR reveals that the extent of the cis influence on the Co-CH2 resonance is more in the case of the dicobaloxime but it is nearly same for the P-alpha and the P-gamma resonances.

  DOI：

  10.1016/s0022-328x(96)06885-4