imidazolide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) | 179930-25-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: imidazolide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)
• CAS: 179930-25-7
• 化学式: C₅₁H₃₉N₇ORu
• 分子量: 866.987
• InChiKey: DPPZVPOCJJFMQW-KDTBAHQYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (carbonyl-κC)(methanol-κO)(5,10,15,20-tetra-p-tolylporphyrinato-κ(4)N)ruthenium(II) 在 DBU 作用下， 以 二氯甲烷 为溶剂， 生成 imidazolide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)
  参考文献：
  名称：

  Synthesis and Axial Ligand Substitution Chemistry of Ru(TTP)(NO)X. Structures of Ru(TTP)(NO)X (X = ONO, OH)

  摘要：

  New complexes of the family Ru(TTP)(NO)X, where TTP = tetra-p-tolylporphyrinato dianion, and X = OMe, Cl, OH, SH, S-p-tolyl, O2CH, ONO, ONO2, N-3, or NCS, have been prepared by a variety of high-yield metathesis techniques from Ru(TTP)(CO)(MeOH). New complexes have been characterized by IR, NMR, and UV spectroscopies as well as by cyclic voltammetry, elemental analysis, and, in two cases, by X-ray crystallography. The two complexes which have been characterized by single-crystal X-ray diffraction, the hydroxide and nitrite complexes 6 and 10 both crystallize in the monoclinic space group P2(1)/n and have Z = 6, with two independent metalloporphyrins in the unit cell, one (ordered) lying on a general position and the other (disordered) with the ruthenium on an inversion center. Acid labilization of the methoxide results in facile substitution kinetics at room temperature and with the exception of the sulfhydryl complex, L = SH, the resulting complexes are air stable and thermally robust species. For example, the formate derivative cannot be decarboxylated thermally or photolytically to give a hydride complex, and the azido complex does not eliminate dinitrogen under similar conditions to give a nitrido complex.

  DOI：

  10.1021/ic980182m

文献信息

• Synthesis, structure and ligand exchange reactions of Ru(TTP)(NO)(OMe)
  作者：D. Scott Bohle、Patricia A. Goodson、Bryan D. Smith

  DOI：10.1016/0277-5387(96)00090-3

  日期：1996.6

  A facile, novel preparation of the useful synthon Ru(TTP)(NO)(OMe) is reported and it has been characterized by a range of techniques, including single crystal X-ray diffraction. Subsequent methoxide substitution reactions led to the preparation in high yield and purity of a wide variety of new complexes including a mercaptide complex which is the first reported analogue of the diamagnetic nitrosyl

  报道了一种有用的合成子Ru（TTP）（NO）（OMe）的简便，新颖的制备方法，并已通过包括单晶X射线衍射在内的多种技术进行了表征。随后的甲醇取代反应导致高产率和高纯度的各种新配合物的制备，包括硫醇配合物，该硫醇配合物是P-450单加氧酶的反磁性亚硝酰基加合物的第一个报道类似物。