trans-[Ru(NH3)4(P(OC2H5)3)2](2+) | 64939-00-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: trans-[Ru(NH3)4(P(OC2H5)3)2](2+)
• 英文别名: trans-[Ru(NH3)4(P(OEt)3)2](2+)
• CAS: 64939-00-0
• 化学式: C₁₂H₄₂N₄O₆P₂Ru
• 分子量: 501.506
• InChiKey: ZNOILIRSRZRJCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[Ru(NH3)4(P(OC2H5)3)2](2+) 在 三氟乙酸 作用下， 以 水 为溶剂， 生成 tetraaminobis(triethoxy-l5-phosphaneyl)ruthenium(IX)
  参考文献：
  名称：

  Synthesis, characterization and reactivity of trans-[Ru(NH3)4[P(OEt)3]2]3+ ions

  摘要：

  Trans-[Ru(NH3)4{P(OEt)3}2]3+ ions were generated by electrochemical oxidation of the corresponding trans-[Ru(NH3)4{P(OEt)3}2]2+ ions. The oxidation is quantitative and reversible and the resulting complex absorbs at 292 nm (epsilon = 5.9 x 10(2) M-1 cm-1). ESR spectra of frozen solutions are compatible with axial symmetry D4h, with g(parallel-to) = 1.83 and g(perpendicular-to) = 2.36. Aqueous solutions of the ruthenium(III) complex yield trans-[Ru(NH3)4{P(OEt)3}(H2O)]2+ as the main product upon ageing.

  DOI：

  10.1016/s0277-5387(00)81556-9

文献信息

• Mazzetto, Selma Elaine; De Almeida Plicas, Lidia Maria; Tfouni, Elia, Inorganic Chemistry, 1992, vol. 31, # 3, p. 516 - 519
  作者：Mazzetto, Selma Elaine、De Almeida Plicas, Lidia Maria、Tfouni, Elia、Franco, Douglas Wagner

  DOI：——

  日期：——
• Selective Photolabilization in <i>trans</i>-[Ru(NH₃)₄(P(III))H₂O]²⁺ and <i>trans</i>-[Ru(NH₃)₄(P(OR)₃)₂]²⁺ Complexes (P(III) = P(OR)₃, P(R)₃)
  作者：Selma E. Mazzetto、Elia Tfouni、Douglas W. Franco

  DOI：10.1021/ic9509847

  日期：1996.1.1

  Irradiation in the LF bands (1)A(1) --> (1)E(1) and (1)A(1g) --> (1)A(2g), (1)E(g) leads to NH3 photolabilization of trans-[Ru(NH3)(4)(P(III))H2O](2+) complexes and to NH3 and P(III) photolabilization of trans-[Ru(NH3)(4)(P(III))(2)](2+) species. For both series of complexes Phi(NH3) has essentially the same experimental value of 0.34 +/- 0.03 mol/einstein. The Phi(P(III)) values for the bis(phosphane) complexes trans-[Ru(NH3)(4)(P(III))(2)](2+) are in the 0.034-0.070 range for P(III) = P(OCH3)(3) and P(OC2H4Cl)(3). No clear relationship could be established between the cone angle theta of the phosphane or the formal potential E degrees'(Ru(III)/Ru(II)) and the corresponding Phi(NH3) and Phi(P(III)) data for the complexes studied. The NH3 ligand is selectively photolabilized when the trans-[Ru(NH3)(4)(P(III))(2)](2+) and the trans-[Ru(NH3)(4)(P(III))H2O](2+) species are irradiated with energies corresponding to the (1)A(1g) --> (1)A(2g) and (1)A(1) --> (1)A(2) transitions.