(2,2'-[4,5-dimethyl-1,2-phenylenebis(nitrilomethylidyne-N)]bis(thiophenoato-S))nickel(II) | 184355-57-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,2'-[4,5-dimethyl-1,2-phenylenebis(nitrilomethylidyne-N)]bis(thiophenoato-S))nickel(II)
• 英文别名: [N,N'-bis(2-thiobenzylidene)-1,2-dimethyl-4,5-phenylenediaminato]nickel(II)；Ni(tsaldimph)
• CAS: 184355-57-5
• 化学式: C₂₂H₁₈N₂NiS₂
• 分子量: 433.22
• InChiKey: SRSQNQNCRRUXGC-XSEMBQBTSA-L

反应信息

• 作为产物：
  描述：

  nickel tetrafluoroborate 、 以 乙醇 为溶剂， 生成 (2,2'-[4,5-dimethyl-1,2-phenylenebis(nitrilomethylidyne-N)]bis(thiophenoato-S))nickel(II)
  参考文献：
  名称：

  [N,N'-Bis(2-thiobenzylidene)-1,2-dimethyl-4,5-phenylenediaminato]nickel(II), Ni(tsaldimph)

  摘要：

  {2,2'-[4,5-Dimethyl-1,2-phenylenebis(nitrilomethylidyne-N) ]bis(thiophenolato-S)}nickel(II), [Ni(C22H18N2S2)], is a square-planar NiN2S2 complex, formed from a Schiff base reaction of 2-tert-butylthiobenzaldehyde with 1,2-dimethyl-4,5-phenylenediamine, followed by coordination with nickel tetrafluoroborate. It crystallizes in the orthorhombic space group Pbcn, with Ni--N distances of 1.920 (3) Angstrom and Ni--S distances of 2.174 (1) Angstrom.

  DOI：

  10.1107/s0108270196009778