[Cu(I)(2-(2-(6-methylpyridyl))-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy)2](PF6) | 155311-37-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(I)(2-(2-(6-methylpyridyl))-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy)2](PF6)
• CAS: 155311-37-8
• 化学式: C₂₆H₃₆CuN₆O₂*F₆P
• 分子量: 673.121
• InChiKey: QZAZEUKBGVAXKJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-(6'-methyl-2'-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 以 乙醇 为溶剂， 生成 [Cu(I)(2-(2-(6-methylpyridyl))-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy)2](PF6)
  参考文献：
  名称：

  Oshio, Hiroki; Watanabe, Takashi; Ohto, Akihiro, Angewandte Chemie, 1994, vol. 106, p. 691 - 692

  摘要：

  DOI：

文献信息

• Ferromagnetic Interactions between Imino Nitroxides through Diamagnetic Metal Ions:  Crystal Structures, Magnetism, and Electronic Properties of [M^I(imino nitroxide)₂](PF₆) (M = Cu^I and Ag^I)
  作者：Hiroki Oshio、Takashi Watanabe、Akihiro Ohto、Tasuku Ito、Tadaaki Ikoma、Shozo Tero-Kubota

  DOI：10.1021/ic960939e

  日期：1997.7.1

  An orthogonal arrangement of imino nitroxide ligands in Cu-I and Ag-I complexes results in propagation of an intramolecular ferromagnetic interaction between the coordinated imino nitroxides through these diamagnetic ions. Reaction of [Cu-I(CH3CN)(4)](PF6) and Ag-I(PF6) with imino nitroxides in ethanol solution gave [Cu-I(immepy)(2)-(PF6) (1) and [Ag-I(impy)(2)](PF6) (2), respectively (immepy 2-(2-(6-methylpyridyl))-4,4,5,5-tetramethyl-4,5-dihydro-1H imidazolyl-l-oxy and impy 2-(2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy). Complex 1 crystallizes in the orthorhombic space group Pba2, which has a unit cell with a 11.251(2) Angstrom, b = 14.745(3) Angstrom, c = 9.747(2) Angstrom, V = 1617.0(5) Angstrom(3), and Z = 2. Refinement with 991 reflections observed [\I-0\ > 3 sigma(I-0)] gave R = 0.044 (R-w = 0.053). In 1, imino nitroxides coordinate to the Cu-I ions in a tetrahedral fashion, the dihedral angle between coordinating imino nitroxides being 88.7 degrees. Magnetic susceptibility measurement for 1 shows typical triplet-singlet behavior with strong ferromagnetic interactions (J = 55.1(6) cm(-1) with g = 2.0; H = -JS(1).S-2) The UV-visible absorption spectrum of 1 shows strong bands at 454 and 766 nm assignable to charge-transfer bands from the Cu ion to the ligand NLUMO and SOMO, respectively. The pi-back-donation to the SOMO induces the spin on the Cu ion and results in the strong ferromagnetic interaction. Complex 2 crystallizes in the orthorhombic space group P2(1)cn which has a unit cell with a = 10.535(6) Angstrom, b = 31.295(3) Angstrom, c 8.921(4) Angstrom, V = 2941(1) Angstrom(3), and Z = 4. Refinement with 1882 reflections [\I-0\ > 3 sigma(I-0)] gave R = 0.058 (R-w = 0.074). Ln 2, the four coordination sites of the Ag-I ion were completed with two imino nitroxides and the dihedral angle between the imino nitroxides is 79.2 degrees. The EPR spectrum of a frozen ethanol solution of 2 shows a typical triplet signal with zero field splitting (\D\ = 0.043 cm(-1) and \E\ = 0.014 cm(-1)). Curie plots for the rim = 2 signal below 80 K gave a positive Weiss constant (theta = 4 K), suggesting an intramolecular ferromagnetic interaction in 2.