N-([1,1'-biphenyl]-4-yl)spiro[cyclohexane-1,9'-fluorene]-2'-amine | 897671-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: N-([1,1'-biphenyl]-4-yl)spiro[cyclohexane-1,9'-fluorene]-2'-amine
• 英文别名: N-(4-phenylphenyl)spiro[cyclohexane-1,9'-fluorene]-2'-amine
• CAS: 897671-67-9
• 化学式: C₃₀H₂₇N
• 分子量: 401.551
• InChiKey: JWZDLMYMZOSQQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-([1,1'-biphenyl]-4-yl)spiro[cyclohexane-1,9'-fluorene]-2'-amine 、 在 三叔丁基膦 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以3.12 g的产率得到
  参考文献：
  名称：

  一种芳胺化合物及其有机电致发光器件

  摘要：

  本发明涉及有机光电材料技术领域，具体涉及一种芳胺化合物及其有机电致发光器件。本发明提供的式(I)所述的芳胺化合物具有很好的热稳定性、成膜性和空穴传输能力，具有相对于其他功能层，特别是发光层更适当的HOMO和T1值，能够有效避免在发光层与空穴传输区域之间的界面发光，从而降低有机材料因界面发光而受热老化的速度，进而改善器件的驱动电压、发光效率及使用寿命。

  公开号：

  CN113429370A

文献信息

• Aromatic Amine Derivative and Organic Electroluminescent Device Using Same
  申请人：Yabunouchi Nobuhiro

  公开号：US20080108811A1

  公开（公告）日：2008-05-08

  Provided are a novel aromatic amine derivative having an asymmetric structure and an organic electroluminescence device in which, an organic thin film layer comprising a single layer or plural layers including at least a light emitting layer is interposed between a cathode and an anode, at least one layer in the above organic thin film layer contains the aromatic amine derivative described above in the form of a single component or a mixed component, whereby molecules are less liable to be crystallized; a yield in producing the organic electroluminescence device is enhanced; and a lifetime is extended.

  提供了一种具有不对称结构的新型芳香胺衍生物和一种有机电致发光器件，其中，在阴极和阳极之间夹有包括至少一个发光层的单层或多层有机薄膜层，上述有机薄膜层中的至少一层以单一组分或混合组分的形式含有上述芳香胺衍生物，从而分子不容易结晶；提高了有机电致发光器件的产量；并延长了寿命。
• DERIVATE VON 2-DIARYLAMINOFLUOREN UND DIESE ENTHALTNDE ORGANISCHE ELEKTRONISCHE VERBINDUNGEN
  申请人：Merck Patent GmbH

  公开号：EP2875699B1

  公开（公告）日：2017-02-15
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：YABUNOUCHI Nobuhiro

  公开号：US20120112176A1

  公开（公告）日：2012-05-10

  Disclosed is an organic electroluminescence device in which an organic thin film which is composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode. Since at least one layer of the organic thin film contains a novel aromatic amine derivative, which has an asymmetric structure wherein two different amine units are bonded through a linking group, by itself or as a component of a mixture, molecules are hardly crystallized, thereby improving the production yield of the organic electroluminescence device. This organic electroluminescence device has a long life.
• Compounds and Organic Electronic Devices
  申请人：Merck Patent GmbH

  公开号：US20170317285A1

  公开（公告）日：2017-11-02

  The present invention relates to certain fluorenes, to the use of the compounds in an electronic device, and to an electronic device comprising at least one of these compounds. The present invention furthermore relates to a process for the preparation of the compounds and to a formulation and composition comprising one or more of the compounds.
• US8629613B2
  申请人：——

  公开号：US8629613B2

  公开（公告）日：2014-01-14