| 1204570-71-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1204570-71-7
• 化学式: C₁₂H₂₄KO₆*C₂₀H₁₄F₁₂O₂P
• 分子量: 848.702
• InChiKey: PNJZODYULBPZGK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  18-冠醚-6 、 2-[2-(1,1-Dimethyl-3,3-bis-trifluoromethyl-2-oxa-1λ⁵-phospha-indan-1-yl)-phenyl]-1,1,1,3,3,3-hexafluoro-propan-2-ol 在 potassium hydride 作用下， 以 二氯甲烷 为溶剂， 反应 0.17h， 以82%的产率得到
  参考文献：
  名称：

  Solution and Crystal Structure of a Hexacoordinate Phosphoranate Bearing Two Martin Ligands and Two Methyl Groups

  摘要：

  A hexacoordinate phosphoranate bearing two Martin ligands and two methyl groups was synthesized by the reaction of the monocyclic phosphorane bearing a hydroxy group with KH, and was crystallized in the presence of 18-crown-6 ether. The crystal structure of the phosphoranate could be regarded as an intermediate model in the reaction of the O-equatorial methylphosphorane with a methyl anion.

  DOI：

  10.1080/10426500902718265