5,7-dioxo-6-(2-pyridyl)-6,7-dihydro-5H-dibenzo[a,c]cycloheptene | 950912-91-1

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 5,7-dioxo-6-(2-pyridyl)-6,7-dihydro-5H-dibenzo[a,c]cycloheptene
• CAS: 950912-91-1
• 化学式: C₂₀H₁₃NO₂
• 分子量: 299.329
• InChiKey: FYNSRFAZMQFIMX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  5,7-dioxo-6-(2-pyridyl)-6,7-dihydro-5H-dibenzo[a,c]cycloheptene 、 copper(II) nitrate 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Structure of six- and seven-membered cyclic- β-diketones and their metal(II) complexes

  摘要：

  Two new copper(II) complexes with physiologically active ligands containing both pyridine ring and cyclic P-diketones with different ring members were obtained with the metal to ligand ratio 1:2. The structure and coordination mode of both complexes were studied using IR and EPR methods. The AM1 method was applied for calculating the structure of 5,7-dioxo-6-(2-pyridyl)-6,7-dihydro-5H-dibenzo (a,c)cycloheptene and its Zn-II complex. It is shown that the structure of both complexes is a tetragonal one and the coordination is realized via the hydroxy O and N of the pyridine ring. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00472-x