| 142359-15-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• CAS: 142359-15-7
• 化学式: C₂₈H₂₉O₉PRuS₄
• 分子量: 769.841
• InChiKey: UMTOBHJLIWGEKD-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  在 P(C₆H₅)3 作用下， 以 1,4-二氧六环 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  Synthesis, characterization of mono- and binuclear ruthenium(II) complexes with the potential O and S donor ligand 1,1′,2,2′- ethanetetra(thioglycolic acid) and their reactivity with π-acidic ligands

  摘要：

  Synthesis of mono- and binuclear Ru(II) complexes of the composition [RuL(H2O)] (1) and [Ru2L(H2O)2] (2), where L = 1, 1',2,2'-ethanetetra(thioglycolic acid), are reported. The interactions of 1 and 2 with the pi-acidic ligands such as CO, PPh3 and NO+ form octahedral species. The complexes were characterized by elemental analysis, IR, UV-vis, 1[H], C-13{H-1} and P-31{H-1} NMR spectroscopy, conductance measurements and differential pulse voltammograms. The redox potential, ruthenium(II)/ruthenium(I), of the complexes become more positive with an increase in the pi-acidity of the ligand coordinated to the metal ion.

  DOI：

  10.1016/s0277-5387(00)84474-5