| 356551-58-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 356551-58-1
• 化学式: C₁₇H₁₆N₂NiO₄
• 分子量: 371.015
• InChiKey: AOYLWCAOJGMGJW-YYRRLPANSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-bis(3-hydroxysalicylidene)-1,2-diaminopropane 、 镍 以 乙腈 为溶剂， 以42%的产率得到
  参考文献：
  名称：

  Co(II), Ni(II) and Cu(II) mononuclear and polynuclear complexes influenced by the aliphatic spacer length of their O2N2O2 Schiff bases

  摘要：

  M(H2Ln)(H2O)(x) and [M-2(L-n)(H2O)(x)](n) have been obtained by the electrochemical reaction of Co, Ni and Cu anodes with the O2N2O2 symmetrical ligands: N,N'-bis(3-hydroxysalicylidene)-1,2-diaminopropane H4L1, N,N ' -bis(3-hydroxysalicylidene)-1,3-diaminopropane, H4L2, and N,N ' -bis(3-hydroxysalicylidene)-1,4-diaminobutane H4L3. The preferential attainment of mono- or polynuclear compounds seems to be conditioned by the aliphatic spacer length, among other factors.Spectroscopic and magnetic data suggest a distorted tetrahedral array in mono- and polynuclear nickel complexes with H4L2 and H4L3. However, when the aliphatic spacer is shorter, as occurs in Ni(H2L1), physicochemical data are consistent with a square planar geometry. The EPR data for polynuclear copper complexes display the characteristics of quasi-axial symmetry and show spin-spin interactions. Magnetic and electronic data point to high-spin distorted octahedral environments for Co(II) ions in [Co-2(L-3)(H2O)(4)](n). (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00407-8