2-(2-Methylpropyl)benzene-1-peroxol | 521292-73-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-Methylpropyl)benzene-1-peroxol
• 英文别名: 1-hydroperoxy-2-(2-methylpropyl)benzene
• CAS: 521292-73-9
• 化学式: C₁₀H₁₄O₂
• 分子量: 166.22
• InChiKey: KMGVYWXLTFCNRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Crystalline MWW-type titanosilicate catalyst for producing oxidized compound, production process for the catalyst, and process for producing oxidized compound by using the catalyst
  申请人：SHOWA DENKO K.K.

  公开号：US20040034258A1

  公开（公告）日：2004-02-19

  A crystalline titanosilicate catalyst which is usable as a catalyst in the oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group, a process for producing the catalyst, and a process for producing an oxidized compound by an oxidation reaction using the catalyst. It has been found that a crystalline titanosilicate having a structural code of MWW effectively functions as a catalyst in an oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group, or a compound having a carbon-carbon double bond a functional group and having a total carbon number of not smaller than 2 and not larger than 5, wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent, thereby to highly selectively provide an intended oxidized compound.

  一种结晶钛硅酸盐催化剂，可用作氧化含有碳碳双键和至少一个其他官能团的化合物的反应中的催化剂，以及生产该催化剂的方法，以及使用该催化剂进行氧化反应生产氧化化合物的方法。已经发现，具有MWW结构代码的结晶钛硅酸盐有效地作为催化剂在氧化含有碳碳双键和至少一个其他官能团的化合物的反应中发挥作用，或者在具有碳碳双键和一个官能团且总碳数不小于2且不大于5的化合物中，通过使用过氧化物作为氧化剂氧化化合物的碳碳双键，从而高度选择性地提供预期的氧化化合物。
• Crystalline mww-type titanosilicate catalyst for producing oxidized compound, production process for the catalyst, and process for producing oxidized compound by using the catalyst
  申请人：——

  公开号：US20030040649A1

  公开（公告）日：2003-02-27

  A crystalline titanosilicate catalyst which is usable as a catalyst in the oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group, a process for producing the catalyst, and a process for producing an oxidized compound by an oxidation reaction using the catalyst. It has been found that a crystalline titanosilicate having a structural code of MWW effectively functions as a catalyst in an oxidation reaction of a compound having a carbon-carbon double bond and at least one other functional group wherein the carbon-carbon double bond of the compound is oxidized by using a peroxide as an oxidizing agent, thereby to highly selectively provide an intended oxidized compound.

  一种结晶的钛硅酸盐催化剂，可用作氧化含有碳碳双键和至少一个其他官能团的化合物的催化剂，在使用该催化剂进行氧化反应的过程中，发现具有MWW结构代码的结晶钛硅酸盐有效地在氧化含有碳碳双键和至少一个其他官能团的化合物的反应中作为催化剂发挥作用，其中使用过氧化物作为氧化剂氧化化合物的碳碳双键，从而高度选择性地提供预期的氧化化合物。生产该催化剂的方法以及使用该催化剂进行氧化反应生产氧化化合物的方法。
• [EN] CYCLOALKANE OXIDATION CATALYSTS AND METHOD TO PRODUCE ALCOHOLS AND KETONES<br/>[FR] CATALYSEURS D'OXYDATION DE CYCLOALCANE ET PROCÉDÉ POUR PRODUIRE DES ALCOOLS ET DES CÉTONES
  申请人：RHODIA OPERATIONS

  公开号：WO2014015491A1

  公开（公告）日：2014-01-30

  Disclosed is a method of oxidizing a cycloalkane to form a product mixture containing a corresponding alcohol and ketone, said method comprising contacting a cycloalkane with a hydroperoxide in the presence of a catalytic effective amount of a crystalline MWW-type titanosilicate catalyst. Hydroperoxides may notably be tert-butyl hydroperoxide, tert-amyl hydroperoxide, cumene hydroperoxide, ethylbenzene hydroperoxide, cyclohexyl hydroperoxide, methylcyclohexyl hydroperoxide, tetralin hydroperoxide, isobutylbenzene hydroperoxide, and ethylnaphthalene hydroperoxide.

  揭示了一种将环烷烃氧化为含有相应醇和酮的产物混合物的方法，该方法包括将环烷烃与过氧化氢化合物在存在晶体MWW型钛硅酸盐催化剂的情况下接触。过氧化氢化合物可以是叔丁基过氧化氢、叔戊基过氧化氢、异丙苯过氧化氢、乙基苯过氧化氢、环己基过氧化氢、甲基环己基过氧化氢、四氢萘过氧化氢、异丁基苯过氧化氢和乙基萘过氧化氢。
• PROCESS FOR THE EPOXIDATION OF OLEFINS
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160083360A1

  公开（公告）日：2016-03-24

  The subject invention is related to a process for the epoxidation of olefin with peroxide, comprising reacting peroxide with olefin in the presence a solvent, wherein the solvent has Hansen Solubility Parameters (HSPs) of δ T,solvent and δ H,solvent and the epoxide product has Hansen Solubility Parameters (HSPs) of δ T,product and δ H,product , and wherein: δ T,product −6≦δ T,solvent ≦δ T,product +6, and δ H,product −6≦δ H,solvent .

  该发明涉及一种过氧化物与烯烃进行环氧化反应的方法，包括在溶剂存在的情况下，将过氧化物与烯烃反应，其中溶剂具有Hansen溶解度参数（HSPs）δT，溶剂和δH，溶剂，环氧产物具有Hansen溶解度参数（HSPs）δT，产物和δH，产物，并且满足以下条件：δT，产物-6≦δT，溶剂≦δT，产物+6，以及δH，产物-6≦δH，溶剂。
• METHOD FOR PRODUCING OXIDIZED COMPOUND
  申请人：Kawabata Tomonori

  公开号：US20110282082A1

  公开（公告）日：2011-11-17

  A method for producing an oxidized compound according to the present invention comprises reacting an organic compound with an oxidizing agent in the presence of titanosilicate (I) or a silylated form thereof, the titanosilicate (I) being obtained by contacting titanosilicate (II) with a structure-directing agent, and the titanosilicate (II) having an X-ray diffraction pattern reproduced in the form of interplanar spacings d of 1.24±0.08 nm, 1.08±0.03 nm, 0.9±0.03 nm, 0.6±0.03 nm, 0.39±0.01 nm and 0.34±0.01 nm.

  根据本发明，生产氧化物的方法包括在钛硅酸盐(I)或其硅烷化形式的存在下，将有机化合物与氧化剂反应，所述钛硅酸盐(I)是通过将钛硅酸盐(II)与结构定向剂接触而获得的，所述钛硅酸盐(II)具有以1.24±0.08纳米、1.08±0.03纳米、0.9±0.03纳米、0.6±0.03纳米、0.39±0.01纳米和0.34±0.01纳米的间隙距离形式再现的X射线衍射图案。