quinuclidin-1-ium diazidotriphenylstannate(IV) | 201135-88-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: quinuclidin-1-ium diazidotriphenylstannate(IV)
• CAS: 201135-88-8
• 化学式: C₇H₁₄N*C₁₈H₁₅N₆Sn
• 分子量: 546.262
• InChiKey: CNVDLWLVHOBZHT-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  奎宁环 、 叠氮(三苯基)锡烷 在 H₂O 作用下， 以 正己烷 为溶剂， 以87%的产率得到quinuclidin-1-ium diazidotriphenylstannate(IV)
  参考文献：
  名称：

  Piperidinium Diazidotriphenylstannate and Quinuclidinium Diazidotriphenylstannate

  摘要：

  Two triphenyltin-azide adducts with cyclic aliphatic amines are shown by X-ray diffraction to be [LH][(C6H5)(3)Sn(N-3)(2)], where for (I), L = piperidine (C5H11N), and for (II), L = quinuclidine (C7H13N). The anions have quasi-trigonal-bipyramidal symmetry, with the azide groups occupying axial positions. In each case, the azide groups are non-equivalent due to one of them hydrogen bonding with the cation. In (I), the NH2 of the cation hydrogen bonds with azides of adjacent anions forming chains through the lattice. For (II), the asymmetric unit has two cations and anions. One cation singly hydrogen bonds to an azide group of one anion, while the other cation forms a bifurcated hydrogen bond linked to azide groups on the two different anions. The cations have their usual geometries, the piperidinium ion having the expected chair conformation.

  DOI：

  10.1107/s010827019700958x