{Ni((o-OC6H4CH=NC2H4)2S2) | 86330-29-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: {Ni((o-OC6H4CH=NC2H4)2S2)
• CAS: 86330-29-2；86322-80-7
• 化学式: C₁₈H₁₈N₂NiO₂S₂
• 分子量: 417.175
• InChiKey: LLVSUFPJUSDZKE-WKLZLTIDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel diacetate 、 2,2'-bisphenol 以 甲醇 为溶剂， 生成 {Ni((o-OC6H4CH=NC2H4)2S2)
  参考文献：
  名称：

  Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides

  摘要：

  On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl)diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.

  DOI：

  10.1134/s1070363209030128

文献信息

• Synthesis, characterization and electrochemistry of nickel(II) complexes of Schiff base ligands containing a disulphide group. Crystal structure of [Ni{(o-OC6H4CHNC6H4)2S2}(MeOH)] · MeOH
  作者：C. Manzur、C. Bustos、R. Schrebler、D. Carrillo、C.B. Knobler、P. Gouzerh、Y. Jeannin

  DOI：10.1016/s0277-5387(00)81260-7

  日期：1989.1

  disulphide ligands N,N′-[1,1′-dithiobis(phenylene)]bis(salicylideneimine), designated hereunder as H2salps, and N,N′-[1,1′-dithiobis(ethylene)]bis(salicydeneimine), designated hereunder as H2sales, react with nickel(II) acetate tetrahydrate in methanol giving two mononuclear complexes: [Ni(salps)(MeOH)] · MeOH and [Ni(sales)], respectively. These complexes have been characterized by spectral, magnetic and

  摘要席夫碱二硫化物配体N，N'-[1,1'-二硫代双（亚苯基）]双（水杨亚胺），以下称为H2salps，以及N，N'-[1,1'-二硫代双（乙烯）]双（水杨醛亚胺），在下文中称为H 2销售，与乙酸镍（II）四水合物在甲醇中反应，得到两种单核络合物：[Ni（salps）（MeOH）]·MeOH和[Ni（sales）]。这些配合物已通过光谱，磁性和电化学方法进行了表征。[Ni（salps）（MeOH）]·MeOH的结构已通过X射线衍射分析确定。该复合物在三斜晶系晶体中结晶，空间群P1，Z = 2，a = 9.476（1），b = 11.297（3）和c = 13.215（3）A，α= 106.66（1），β= 97.10（ 1），并且γ= 99.94（1）°和V = 1312.3（3）A3。基于2 599次反射（I⪢3σ（I）），细化收敛到R = 0.034和Rw = 0.045。所述悬液用作