oxo[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-κN(4)]vanadium(IV) dichloromathane solvate | 220150-01-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: oxo[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-κN(4)]vanadium(IV) dichloromathane solvate
• 英文别名: vanadyl tetrakis(pentafluorophenyl)porphyrin dichloromethane solvate
• CAS: 220150-01-6
• 化学式: CH₂Cl₂*C₄₄H₈F₂₀N₄OV
• 分子量: 1124.42
• InChiKey: RRFMPDPSIKVGEP-XIHSPRSUSA-N

反应信息

• 作为产物：
  描述：

  tetrakis(pentafluorophenyl)porphyrin 、 bis(acetylacetonate)oxovanadium 以 neat (no solvent) 为溶剂， 生成 oxo[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-κN(4)]vanadium(IV) dichloromathane solvate
  参考文献：
  名称：

  Vanadyl Tetrakis(pentafluorophenyl)porphyrin Dichloromethane Solvate

  摘要：

  The vanadyl complex oxo[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-kappa(4)N] vanadium(Iv) dichloromethane solvate, [VO(C44H8F20N4)]. CH2Cl2, crystallizes in the monoclinic space group P2(1)/c, with four molecules per unit cell. The V atom is found to lie 0.5237(5)Angstrom above the mean plane of the porphyrin core. The average V-N distance is 2.067(5)Angstrom and the V=O bond length is 1.585(2)Angstrom. The doming of the porphyrin core is characteristic of five-coordinate metalloporphyrins. Moreover, the macrocycle is slightly saddle-shaped and ruffled. Van der Waals contacts between the phenyl rings and the solvent molecules lead to dihedral angles between these phenyl rings and the porphyrin core mean plane ranging from 58.23(5) to 89.38(6)degrees. These contacts could explain the deviation of the porphyrin geometry relative to the fourfold symmetry.

  DOI：

  10.1107/s0108270198008038