[PtCl(4'-(3-propoxy)-2,2':6',2''-terpyridine)][BF4] | 390366-32-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [PtCl(4'-(3-propoxy)-2,2':6',2''-terpyridine)][BF4]
• 英文别名: chloroplatinum(1+);4-propoxy-2,6-dipyridin-2-ylpyridine;tetrafluoroborate
• CAS: 390366-32-2
• 化学式: BF₄*C₁₈H₁₇ClN₃OPt
• 分子量: 608.69
• InChiKey: YLPISAHFDDSKFD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氟硼酸钠 、 potassium tetrachloroplatinate(II) 、 Propyl 4'-(2,2':6',2''-terpyridinyl) ether 以 硝基甲烷 为溶剂， 以53%的产率得到[PtCl(4'-(3-propoxy)-2,2':6',2''-terpyridine)][BF4]
  参考文献：
  名称：

  Metal complexes of 4′-(3-phenylpropoxy)-2,2′:6′,2″-terpyridine and 4′-(3-propoxy)-2,2′:6′,2″-terpyridine

  摘要：

  Reaction of 4'-chloro-2,2':6',2"-terpyridine with 3-phenyl-n-propanol or n-propanol in the presence of excess KOH in dmso, respectively, yields 4'-(3-phenylpropoxy)-2,2':6',2"-terpyridine (L-2) and 4'-(3-propoxy)-2,2':6',2"-terpyridine (L-3). The following complexes of these two ligands have been prepared: [{Cu(mu -Cl)L}(2)](BF4)(2), [Cu(NCMe)(L)](BF4)(2), [PdCl(L)]BF4 and [PtCl(L)]BF4 (L = L-2, L-3). Recrystallisation of [Cu(NCMe)(L-2)](BF4)(2) from PhCN/Et2O yields [Cu(NCPh)(L-2)](BF4)(2), whose crystal structure shows a square planar Cu(Il) ion with substantial disorder in the PhCN ligand and 3-phenylpropoxy tail. The single crystal structure of [PdCl(L-2)]BF4. 2CH(3)NO(2) contains a square planar Pd(II) centre. Neither of these structures, nor the solution spectroscopic or electrochemical data from the complexes, provide any evidence for intramolecular pi-pi interactions between the terpyridine ring and phenylpropoxy substituent. (Non-SI unit employed: 1 G = 10(-4) T.) (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00905-6