[(N-(2-[(E)-((2-[((4-methylbenzene)sulfonyl)amino]phenyl)imino)methyl]phenyl)-4-methylbenzenesulfonamidate)(methanole)copper(II)] | 227467-07-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(N-(2-[(E)-((2-[((4-methylbenzene)sulfonyl)amino]phenyl)imino)methyl]phenyl)-4-methylbenzenesulfonamidate)(methanole)copper(II)]
• 英文别名: [(2-N-tosylamino(2'-tosylaminobenzylidene)aniline)(methanole)copper(II)]
• CAS: 227467-07-4
• 化学式: C₂₈H₂₇CuN₃O₅S₂
• 分子量: 613.217
• InChiKey: OJPVQFWVUVMPLC-WJTVRXJYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  铜 、 4-methyl-N-{2-[(2-{[(4-methylphenyl)sulfonyl]amino}benzylidene)amino]phenyl}benzenesulfonamide 在 Et₄NClO₄ 作用下， 以 甲醇 为溶剂， 生成 [(N-(2-[(E)-((2-[((4-methylbenzene)sulfonyl)amino]phenyl)imino)methyl]phenyl)-4-methylbenzenesulfonamidate)(methanole)copper(II)]
  参考文献：
  名称：

  Direct electrochemical synthesis of novel transition metal chelates of tridentate azomethinic ligands

  摘要：

  New chelates of the type ML(L-1)(n). MeOH (n = 1, 2) were obtained on the basis of the tridentate azomethinic ligands 2-N-tosylamine(2'-hydroxybenzal)aniline (L) and 2-N-tosylamine(2'-tosylaminobenzal)aniline (L-1) and zero-valent transition metals (Co, Ni, Cu, Zn, Cd) under electrosynthesis conditions. The mononuclear character of these products and the participation of N2O- or N-3 groups of the azomethinic Ligands in the coordination are demonstrated by IR, H-1 NMR spectral and magnetic data (77-293 K). (C) 1999 Elsevier Science Ltd, All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00383-0

文献信息

• Electrochemical synthesis of adducts of 2-aminopyridine or methanol in metal chelates of a N,N,N-tridentate Schiff base ligand. X-ray crystal structures of the Ni(II) and Zn(II) derivatives
  作者：D.A. Garnovskii、M.F.C. Guedes da Silva、M.N. Kopylovich、A.D. Garnovskii、J.J.R. Fraústo da Silva、A.J.L. Pombeiro

  DOI：10.1016/s0277-5387(03)00104-9

  日期：2003.5

  The electrochemical syntheses of series of novel adducts of 2-aminopyridine and methanol in Co(II), Ni(II), Cu(II) or Zn(II) chelates of the N,N,N-tridentate basic form of the Schiff base 2-N-tosylamino(2'-tosylaminobenzylidene)aniline (H2L), [M(L)L'] (M = Co, Ni, Zn, L' = 2-aminopyridine; M = Cu, L' = CH3OH), were performed by using the corresponding metal as a sacrificial anode. The compounds were characterized by elemental analysis, IR spectroscopy, FAB mass spectrometry, H-1 NMR and magnetic measurements. The crystal structures of the Zn and Ni derivatives as well as of the Schiff base have been determined by X-ray diffraction. In the 2-aminopyridine complexes this ligand is bound to the metal through the endocyclic nitrogen whereas the aminogroup is involved in intramolecular N-(HO)-O-... hydrogen bonds with one of the tosyl SO2 groups. (C) 2003 Elsevier Science Ltd. All rights reserved.