A polyorganosiloxane graft copolymer in which one or more vinyl monomers have been graft-polymerized onto a composite rubber having such a structure that 1 to 10 wt.% of a polyorganosiloxane rubber component and 99 to 90 wt.% of a polyalkyl (meth)acrylate rubber component are tangled with each other so as not to separate, as well as having a gel content of 85% or more and a swelling degree of 3 to 15, both measured with a toluene solvent, and an average particle size of 0.08 to 0.6 µm. The high impact polyorganosiloxane graft copolymer according to the present invention can give molded products having excellent impact resistance and surface hardness, and besides it can form an excellent resin composition by mixing with a particular resin.
一种聚有机
硅氧烷接枝共聚物,其中一种或多种
乙烯基单体已接枝聚合到复合橡胶上,其结构为 1 至 10 wt.% 的聚有机
硅氧烷橡胶成分和 99 至 90 wt.%的聚烷基(甲基)
丙烯酸酯橡胶成分相互缠结而不会分离,同时具有 85% 或以上的凝胶含量和 3 至 15 的膨胀度(均用
甲苯溶剂测量),以及 0.08 至 0.6 µm 的平均粒径。根据本发明的高抗冲聚有机
硅氧烷接枝共聚物可以生产出具有优异抗冲击性和表面硬度的模塑产品,此外,它还可以通过与特定
树脂混合形成优异的
树脂组合物。