[erbium(III)(phthalocyaninato)acetate] | 148484-67-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: [erbium(III)(phthalocyaninato)acetate]
• CAS: 148484-67-7
• 化学式: C₂H₃O₂*C₃₂H₁₆N₈*Er
• 分子量: 738.837
• InChiKey: YPLXDSQQMIPEMY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  erbium(III) acetate 、 1,2-二氰基苯 以 melt 为溶剂， 生成 [erbium(III)(phthalocyaninato)acetate]
  参考文献：
  名称：

  Kirin, I. S.; Moskalev, P. N.; Makashev, Yu. A., Zhurnal Neorganicheskoi Khimii, 1964, vol. 10, p. 1065 - 1066

  摘要：

  DOI：

文献信息

• Sandwich double-decker Er(<scp>iii</scp>) and Yb(<scp>iii</scp>) complexes containing naphthalocyanine moiety: synthesis and investigation of the effect of a paramagnetic metal center
  作者：Tatiana V. Dubinina、Anton D. Kosov、Elizaveta F. Petrusevich、Nataliya E. Borisova、Alexander L. Trigub、George V. Mamin、Ildar F. Gilmutdinov、Artem A. Masitov、Sergey V. Tokarev、Victor E. Pushkarev、Larisa G. Tomilova

  DOI：10.1039/c9dt03226f

  日期：——

  diamagnetic Lu(III) complexes. In the near-IR absorption spectra, an increase in ionic radius from Lu(III) to Er(III) resulted in a bathochromic shift of the intervalence band up to 1473 nm. This work presents the first experimental EPR study of Yb(III) bis naphthalocyaninate, where a set of magnetic parameters and properties (including spin, magnitude and sign of magnetic anisotropy parameter D, increased

  合成了新型的含有八-苯基或八-苯氧基取代的萘酞菁的杂芳族Er（III）和Yb（III）萘酞菁-酞菁酸酯，并通过1 H NMR，EPR和高分辨率MALDI-TOF / TOF质谱进行了鉴定。进行了新的均化Yb（III）双（八-苯基萘酞菁）的直接合成。与相应的反磁性Lu（III）配合物相比，观察到了镧系元素低场诱导的质子在目标化合物中的转移。在近红外吸收光谱中，从Lu（III）到Er（III）的离子半径增加导致间隔的红移波段高达1473 nm。这项工作是对Yb（III）双萘酞菁酸酯的首次实验性EPR研究，其中一组磁学参数和性质（包括自旋，磁各向异性参数D的自旋，幅度和符号，晶体场中裂变增加，铁磁f-π相互作用等）。）由EPR和SQUID技术确定和解释，并得到理论上的考虑。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sc: MVol.D1, 2.23.7, page 96 - 99
  作者：

  DOI：——

  日期：——
• Lomova, T. N.; Andrianova, L. G., Russian Journal of Inorganic Chemistry, 1994, vol. 39, p. 1926 - 1931
  作者：Lomova, T. N.、Andrianova, L. G.

  DOI：——

  日期：——
• Axial ligands and (acido) (phthalocyaninato) lanthanides(III) stability on examples of erbium and lutetium
  作者：T. N. Lomova

  DOI：10.1134/s107036321504026x

  日期：2015.4

  The results of a spectrophotometric study of the dissociation kinetics of the coordination centre in (phthalocyaninato) erbium(III) and lutetium(II), (X)LnPc (X = Cl, Br, AcO) in ethanol in the presence of acetic acid are reported. The kinetic equations, the numerical values of reaction rate constants and dependences of the letter on the temperature were determined by the method of excessive concentrations. The stoichiometric mechanism of the complexes dissociation and the nature of the limiting elementary reaction were substantiated and the role of axial ligands in the reaction mechanism was revealed using spectral data and the quasiequilibrium principle to describe kinetic regularities. The resulting data can help in the use of erbium and lutetium phthalocyanines as precursors in the synthesis of higher stoichiometry complexes.