(S)-[4-(2-n-decyloxy)propionyloxy]benzoic acid | 387884-02-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: (S)-[4-(2-n-decyloxy)propionyloxy]benzoic acid
• CAS: 387884-02-8
• 化学式: C₂₀H₃₀O₅
• 分子量: 350.455
• InChiKey: PTFVFHCJXBSCAD-INIZCTEOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.84
• 重原子数：
  25.0
• 可旋转键数：
  13.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  72.83
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (S)-[4-(2-n-decyloxy)propionyloxy]benzoic acid 、 4-羟苯基-4-(癸基氧基)苯甲酸盐 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 生成 (S)-[4-n-decyloxybenzoyloxyphenyl]-4'-[(2-n-decyloxy)propionyloxy]benzoate
  参考文献：
  名称：

  Synthesis and Liquid Crystalline Properties of (S)-[4-n-Alkyloxy-benzoyloxyphenyl]-4′-[(2-n-alkyloxy)propionyloxy]benzoate

  摘要：

  New series of chiral liquid crystalline compounds, (S)-[4-n-alkyloxy-benzoyloxyphenyl]-4'-[(2-n-alkyloxy)propionyloxy]benzoate (QMn/m), were synthesised. Polymorphism of the new compounds was investigated by polarising microscopy and differential scanning calorimetry. All members of the homologous series showed enantiotropic SmC* and N* mesophases except one compound having the longest alkyl chain in both terminal groups. The spontaneous polarisation of these ferroelectric liquid crystalline compounds is about 110-130 nC/cm(2). The temperature dependence of the dielectric permittivity was measured for all the compounds studied. Several ferroelectric binary mixtures were prepared in order to get a wide enantiotropic chiral SmC* phase at ambient temperature.

  DOI：

  10.1080/10587250108025337
• 作为产物：
  描述：

  (S)-2-n-decyloxypropionic acid 、 对羟基苯甲酸 在 zinc(II) chloride 作用下， 以 乙醚 、 吡啶 、 二氯甲烷 为溶剂， 反应 10.0h， 生成 (S)-[4-(2-n-decyloxy)propionyloxy]benzoic acid
  参考文献：
  名称：

  Synthesis and Liquid Crystalline Properties of (S)-[4-n-Alkyloxy-benzoyloxyphenyl]-4′-[(2-n-alkyloxy)propionyloxy]benzoate

  摘要：

  New series of chiral liquid crystalline compounds, (S)-[4-n-alkyloxy-benzoyloxyphenyl]-4'-[(2-n-alkyloxy)propionyloxy]benzoate (QMn/m), were synthesised. Polymorphism of the new compounds was investigated by polarising microscopy and differential scanning calorimetry. All members of the homologous series showed enantiotropic SmC* and N* mesophases except one compound having the longest alkyl chain in both terminal groups. The spontaneous polarisation of these ferroelectric liquid crystalline compounds is about 110-130 nC/cm(2). The temperature dependence of the dielectric permittivity was measured for all the compounds studied. Several ferroelectric binary mixtures were prepared in order to get a wide enantiotropic chiral SmC* phase at ambient temperature.

  DOI：

  10.1080/10587250108025337

文献信息

• NEW FERROELECTRIC LIQUID CRYSTALLINE SUBSTANCES WITH LATERAL GROUPS IN THE CORE
  作者：Alexej Bubnov、Věra Hamplová、Miroslav Kašpar、Přemysl Vaněk、Damian Pociecha、Milada Glogarová

  DOI：10.1080/10587250108023995

  日期：2001.8