[(κ2-2,2′-Bipyridyl-N,N′)(κ3-2,6-di(5-trifluoromethylpyrazol-3-yl)pyridyl-N,N,N′)copper(II)] | 1428232-35-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(κ2-2,2′-Bipyridyl-N,N′)(κ3-2,6-di(5-trifluoromethylpyrazol-3-yl)pyridyl-N,N,N′)copper(II)]
• 英文别名: [(κ²-2,2′-Bipyridyl-N,N′)(κ³-2,6-di(5-trifluoromethylpyrazol-3-yl)pyridyl-N,N,N′)copper(II)]
• CAS: 1428232-35-2
• 化学式: C₂₃H₁₃CuF₆N₇
• 分子量: 564.94
• InChiKey: VOQLCHGLDDEXQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 Tetrakis(κ³-2,6-di(5-trifluoromethylpyrazol-3-yl)pyridyl)tetracopper(II) acetonitrile trisolvate 反应 4.0h， 以89%的产率得到[(κ2-2,2′-Bipyridyl-N,N′)(κ3-2,6-di(5-trifluoromethylpyrazol-3-yl)pyridyl-N,N,N′)copper(II)]
  参考文献：
  名称：

  Neutral tetranuclear Cu(II) complex of 2,6-di(5-trifluoromethylpyrazol-3-yl)pyridine: Synthesis, characterization and its transformation with selected aza-ligands

  摘要：

  New tetranuclear Cu(II) complex [Cu-4(L)(4)]center dot MeCN (1) with 2,6-di(5-trifluoromethyl-1H-pyrazol-3-yl)pyridine (H2L) was synthesized. It has been shown that treatment of 1 with selected aza-ligands (pyridine, 2,2'- and 4,4'-bipyridyl, 2,3,5,6-tetra-(pyridine-2-yl)pyrazine, 2,2';6',2 ''-terpyridine and 1,4-diazabicyclo[2.2.2]octane) leads to formation of other Cu(II) complexes with different nuclearity: [Cu(L)py(2)] (2), [Cu(L)(2,2'-bpy)] (3), [Cu(L)(2)(tPPz)]center dot THF (5), [Cu(L)tpy]center dot C6H5CN (4), {[Cu-2(L)(2)(4,4'-bpy)(2)]center dot(C6H5CH3)center dot MeCN}(n) (6) and {[Cu(L)DABCO]center dot 2MeCN}(n) (7). Obtained compounds were characterized by IR spectroscopy, X-ray crystallography data, EPR and SQUID magnetic measurements. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.021