[Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato))(H2O)]4[Fe(CN)6]ClO4 | 200199-36-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato))(H2O)]4[Fe(CN)6]ClO4
• CAS: 200199-36-6
• 化学式: C₈₆H₉₆FeMn₄N₁₄O₁₂*ClO₄
• 分子量: 1892.84
• InChiKey: INOUJZKRWXIVNJ-LFNFZJDQSA-E

反应信息

• 作为产物：
  描述：

  甲醇 、 tetraethylammonium hexacyanoferrate(III) 、 [Mn₂(N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate))₂(H₂O)₂](ClO₄)₂ 以 甲醇 为溶剂， 生成 [Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato))(H2O)]4[Fe(CN)6]ClO4
  参考文献：
  名称：

  Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures Using a Desolvation Reaction:  Synthesis, Structure, and Magnetic Properties of Manganese(III)−Schiff-Base−Hexacyanoferrate Polymeric Compounds and Their Derived Extended Structures

  摘要：

  [Mn(BS)(H2O)]ClO4 and [NEt4](3)[Fe(CN)(6)] react in methanol or ethanol to give a binuclear [NEt4](2)[{Mn(BS)(S)}(Fe(CN)(6)}], 1, three trinuclear [NEt4][{Mn(BS)(S)}(2){Fe(CN)(6)}], 2-4, and a pentanuclear [Mn(BS)(S)](4)[Fe(CN)(6)]ClO4, 5, heterometal complex, depending on the nature of the quadridentate Schiff-base ligands and regardless of the stoichiometric ratio of the precursor components (BS = saldmen = N,N'-(1,1-dimethylethylene)bis(salicylideneiminato) dianion, S = H2O for 1; BS rac-salmen = rac-N,N'-(1-methylethylene)bis (salicylideneiminato) dianion, S = MeOH for 2; BS = rac-salcy = rac-N,N'-(1,2-cyclohexanediylethylene)bis(salicylideneiminato) dianion, S = MeOH for 3; (R,R)-salcy = (R,R)-N,N'-(1,2-cyclohexanediylethylene)bis (salicylideneiminato) dianion, S = H2O for 4; BS = saltmen = N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneiminato) dianion, S = H2O for 5). Complexes 1 and 2 have been characterized by X-ray analyses, Complex 1 consists of a discrete CN-bridged Mn(III)-Fe(III) binuclear unit [(H2O)Mn(saldmen)Fe(CN)(6)](2-) hydrogen-bonded into a one-dimensional chain structure. Complex 2 consists of a discrete centrosymmetric trinuclear unit [(MeOH)Mn(salmen)Fe(CN)(6)Mn(salmen)(MeOH)](-) hydrogen-bonded, thus forming a two-dimensional network with a repeating cyclic octamer [-NC-Fe-CN-Mn-MeOH-](4) unit. Complexes 1-5 led to desolvated forms 1'-5'. Some of these forms (1'-3') show spontaneous magnetization according to an extended structure where the original magnetically isolated oligomeric forms now communicate with each other, In the case of 4' and 5', the desolvation probably occurs with a severe reorganization of the parent hydrogen-bonded extended structure, and hence, cooperative magnetic effects were not observed.

  DOI：

  10.1021/ic9709640