methanol;tribromoruthenium;triphenylarsane | 50492-96-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methanol;tribromoruthenium;triphenylarsane
• CAS: 50492-96-1
• 化学式: C₃₇H₃₄As₂Br₃ORu
• 分子量: 985.302
• InChiKey: CRLJCKOPKIGYKU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  methanol;tribromoruthenium;triphenylarsane 、 3-(p-tolylimino-methyl)-benzene-1,2-diol 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Schiff base complexes of ruthenium(III), molybdenum(VI) and uranium(VI), and use of the former as catalytic organic oxidants

  摘要：

  The new complexes [RuIIIX2(AsPh3)2(HL)] (X = Cl, Br; HL = monoanions of Schiff bases formed from condensation of 2,3-dihydroxybenzaldehyde and aniline or its omicron- and p-substituted derivatives), cis-[MoO2(HL)2] and trans-[UO2(HL)2.nH2O] (n = 0 or 2) have been isolated. They were characterized by spectroscopic techniques and investigated by cyclic voltammetry. The ruthenium(III) complexes were found to be effective catalysts for oxidation of primary alcohols to aldehydes, secondary alcohols to ketones and 3,5-di(tert-butyl)catechol to the corresponding omicron-benzoquinone in the presence of N-methyl-morpholine-N-oxide as co-oxidant.

  DOI：

  10.1016/s0277-5387(00)83299-4
• 作为产物：
  描述：

  [tris(triphenylarsine) ruthenium(III) tribromide] 在 甲醇 作用下， 以 二氯甲烷 为溶剂， 以90%的产率得到methanol;tribromoruthenium;triphenylarsane
  参考文献：
  名称：

  Electron spin resonance studies of some ruthenium(III) complexes

  摘要：

  DOI：

  10.1021/ic50207a055

文献信息

• New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
  作者：T.A. Stephenson、G. Wilkinson

  DOI：10.1016/0022-1902(66)80191-4

  日期：1966.4

  The interaction of triphenylphosphine, -arsine and -stibine with hydrated ruthenium trichloride in methanol leads to a variety of complexes such as [RuCl2(PPh3)4], [RuCl2(PPh3)3], [RuCl3(PPh3)2CH3OH], [RuCl3(AsPh3)2CH3OH] and [RuCl2(SbPh3)3]. The corresponding bromo complexes are also described. New mono and dicarbonyl complexes of ruthenium (II) and (III) have also been prepared by the interaction

  三苯基膦，-s和-二苯乙烯与甲醇中的水合三氯化钌的相互作用导致形成多种络合物，例如[RuCl 2（PPh 3）4 ]，[RuCl 2（PPh 3）3 ]，[RuCl 3（PPh 3）2 CH 3 OH]，[RuCl 3（AsPh 3）2 CH 3 OH]和[RuCl 2（SbPh 3）3]。还描述了相应的溴配合物。还已经通过Ph 3 P，Ph 3 As，Ph 3 Sb，吡啶等与含羰基溶液的相互作用制备了钌（II）和（III）的新的单和二羰基配合物。描述了顺式和反式-[RuCl 2（CO）2 L 2 ]，[RuCl 2（CO）L 3 ]和[pyH] [RuCl 4 COpy]的配合物。
• Thionitrosyl complexes of ruthenium(II) and their reactions with NOX (X = Cl, Br, Br3, NO2) in presence of excess PPh3, AsPh3, SbPh3 and Py
  作者：K.N. Udupa、K.C. Jain、M.I. Khan、U.C. Agarwala

  DOI：10.1016/s0020-1693(00)81426-7

  日期：1983.1

  mixed thionitrosyl complexes are obtained. On treating these with NOX( X = Cl, Br, Br3) mixed nitrosyl complexes are obtained, presumably through a pentacoordinated species as an intermediate in the presence of excess ligand L′ (L = PPh3, AsPh3; L′ = PPh3, AsPh3, SbPh3, Py). The reactions of dinitrogen trioxide in presence of an excess of the corresponding ligand give nitrosyl nitrato complexes of the

  三氯化三噻唑基在四氢呋喃中与RuCl 2（PPh 3）3，RuBr 2（PPh 3）3，RuCl 3（AsPh 3）2 ·MeOH和RuBr 3（AsPh 3）2 ·MeOH的反应生成结晶硫代亚硝酰基配合物Ru（NS） Cl 3（PPh 3）2，Ru（NS）Br 2 Cl（PPh 3）2，Ru（NS）Cl 3（AsPh 3）2，Ru（NS）Br 2 Cl（AsPh 3）2和两个新颖的混合配体硫代亚硝酰基Ru（NS）Cl 3（PPh 3）AsPh 3和Ru（NS）Cl 3（AsPh 3）（SbPh 3）。在空气中用紫外线照射时，这些化合物形成五配位物种Ru（NS）X 3 L和相应的三苯膦，rs或锑的氧化物。当Ru（NS）X 3 L处理过量的L'时，获得混合的硫代亚硝酰基复合物。通过用NOX（X = Cl，Br，Br 3）处理，可能会在过量配体L'（L = PPh 3，AsPh 3）存在下，通
• Jayakumar, N.; Natarajan, K., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992, vol. 22, p. 349 - 362
  作者：Jayakumar, N.、Natarajan, K.

  DOI：——

  日期：——
• Taqui Khan, M. M.; Rama Rao, E., Polyhedron, 1988, vol. 7, p. 29 - 36
  作者：Taqui Khan, M. M.、Rama Rao, E.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 175, page 474 - 476
  作者：

  DOI：——

  日期：——