| 180298-32-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• CAS: 180298-32-2
• 化学式: C₃₆H₃₂CuN₆S₂
• 分子量: 676.368
• InChiKey: SZRZPLPZWJNCKA-XIJDBYHWSA-N

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 p-[(p-aminophenyl)thio]phenylpyrrole-2-yl-ethylidene 以 乙醇 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Square-Planar Complexes of [p-[(p-Aminophenyl)thio] phenylpyrrole-2-ylethylidene with Co(II), Ni(II), Cu(II) and Pd(II) Metalions

  摘要：

  A new bidentate ligand, [p-l(p-aminophenyl)thio] phenyl pyrrole-2yl-ethylidene [HL] (ATPE), was synthesised from bis-(p-aminophenyl)sulphide and 2-acetylpyrrole. Its metal complexes of the general formula ML(2), where M = Co(II), Ni(II), Cu(II) and Pd(II) have been prepared. On the basis of chemical analyses, magnetic moment measurements, electronic and IR spectra, conductance measurements and pH-metric studies, a square-planar geometry of the ligand around the bivalent metallic ions has been suggested. Some thermodynamic functions, such as changes in free energy (Delta F), entropy (Delta S) and enthalpy (Delta) accompanying the complexation reactions, have been determined. The fungicidal activities of the ligand and its metal complexes have also been studied.

  DOI：

  10.1080/00945719608004353