[nickel(II)(4-thiophenoyphenylglyoxime)2] | 1005756-78-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: [nickel(II)(4-thiophenoyphenylglyoxime)2]
• CAS: 1005756-78-4
• 化学式: C₂₈H₂₂N₄NiO₄S₂
• 分子量: 601.329
• InChiKey: LIIPFLZZAGKNSE-TUGDYTBQSA-L

反应信息

• 作为反应物：
  描述：

  [nickel(II)(4-thiophenoyphenylglyoxime)2] 、 trifluoroborane diethyl ether 以 乙腈 为溶剂， 以75%的产率得到[nickel(II)((4-thiophenoyphenylglyoxime)(BF2))2]
  参考文献：
  名称：

  Synthesis and characterization of new vic-dioximes and their metal complexes with Cu(II), Ni(II), and Co(II) salts

  摘要：

  4-Acetyldiphenyl sulfide and 4.4'-diacetyidiphenyl sulfide were synthesized from diphenyl sulfide and acetyl chloride in the presence of AlCl3 as catalyst in the Friedel-Crafts reaction. Subsequently, the ketooxime and glyoxime derivatives were also prepared. The metal complexes of the glyoximes, such as copper, nickel, and cobalt complexes were prepared. The BF2+ capped Ni(II) mononuclear complex of 4-thiophenoxyphenylglyoxime was prepared. The structures of these ligands were identified by FT-IR, H-1 NMR, and C-13 NMR spectral data and elemental analysis. The structures of the complexes were identified by FT-IR, elemental analysis, and magnetic measurements.

  DOI：

  10.1134/s1070328407030050
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 4-thiophenoxyphenylglyoxime 以 乙醇 、 水 为溶剂， 以87%的产率得到[nickel(II)(4-thiophenoyphenylglyoxime)2]
  参考文献：
  名称：

  Synthesis and characterization of new vic-dioximes and their metal complexes with Cu(II), Ni(II), and Co(II) salts

  摘要：

  4-Acetyldiphenyl sulfide and 4.4'-diacetyidiphenyl sulfide were synthesized from diphenyl sulfide and acetyl chloride in the presence of AlCl3 as catalyst in the Friedel-Crafts reaction. Subsequently, the ketooxime and glyoxime derivatives were also prepared. The metal complexes of the glyoximes, such as copper, nickel, and cobalt complexes were prepared. The BF2+ capped Ni(II) mononuclear complex of 4-thiophenoxyphenylglyoxime was prepared. The structures of these ligands were identified by FT-IR, H-1 NMR, and C-13 NMR spectral data and elemental analysis. The structures of the complexes were identified by FT-IR, elemental analysis, and magnetic measurements.

  DOI：

  10.1134/s1070328407030050