1,4-dichloro-7,8-bis(decyloxy)phenazine-2,3-diol | 1454868-10-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 1,4-dichloro-7,8-bis(decyloxy)phenazine-2,3-diol
• 英文别名: 1,4-Dichloro-7,8-didecoxyphenazine-2,3-diol
• CAS: 1454868-10-0
• 化学式: C₃₂H₄₆Cl₂N₂O₄
• 分子量: 593.634
• InChiKey: QMKBWWRZTNECAU-UHFFFAOYSA-N

物化性质

• 沸点：
  678.1±50.0 °C(predicted)
• 密度：
  1.163±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  40
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  84.7
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  四氟对苯二腈 、 1,4-dichloro-7,8-bis(decyloxy)phenazine-2,3-diol 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 73.0h， 以85%的产率得到2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxo-8,19-dicyanoenneacene
  参考文献：
  名称：

  Synthesis, Characterization, and Nonvolatile Ternary Memory Behavior of a Larger Heteroacene with Nine Linearly Fused Rings and Two Different Heteroatoms

  摘要：

  To achieve ultrahigh density memory devices with the capacity of 3(n) or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyanoenneacene (CDPzN), which has two different types of heteroatoms (O and N) and nine linearly fused rings. The sandwich-structure memory devices based on CDPzN exhibited excellent ternary memory behaviors with high ON2/ON1/OFF current ratios of 10(6.3)/10(4.3)/1 and good stability for these three states.

  DOI：

  10.1021/ja408208c
• 作为产物：
  描述：

  1,2-bis(decyloxy)-4,5-dinitrobenzene 在 palladium 10% on activated carbon 、 一水合肼 作用下， 以 乙醇 为溶剂， 反应 24.0h， 生成 1,4-dichloro-7,8-bis(decyloxy)phenazine-2,3-diol
  参考文献：
  名称：

  Synthesis, Characterization, and Nonvolatile Ternary Memory Behavior of a Larger Heteroacene with Nine Linearly Fused Rings and Two Different Heteroatoms

  摘要：

  To achieve ultrahigh density memory devices with the capacity of 3(n) or larger, organic materials with multilevel stable states are highly desirable. Here, we reported a novel larger stable heteroacene, 2,3,13,14-tetradecyloxy-5,11,16,22-tetraaza-6,10,17,21-tetrachloro-7,9,18,20-tetraoxa-8,19-dicyanoenneacene (CDPzN), which has two different types of heteroatoms (O and N) and nine linearly fused rings. The sandwich-structure memory devices based on CDPzN exhibited excellent ternary memory behaviors with high ON2/ON1/OFF current ratios of 10(6.3)/10(4.3)/1 and good stability for these three states.

  DOI：

  10.1021/ja408208c