| 701922-78-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 701922-78-3
• 化学式: C₁₇H₁₄CuN₂O₄
• 分子量: 373.855
• InChiKey: KILIQGPUGBEOBF-XGMIBILOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 、 cobalt(II) perchlorate hexahydrate 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis, characterization, crystal structures and magnetic properties of dissymmetrical double schiff base heterotrinuclear complexes: [CuL(H2O)CoCuL]·H2O·CH3OH and [(CuL)2Ni]·2H2O

  摘要：

  A dissymmetrical double Schiff base Cu(II) mononuclear complex: CuHL (1) (where H3L is N-3-carboxylsalicylidene-N'-saiicylaldehyde- 1,2-diaminoethane) and two trinuclear complexes: [CuL(H2O)CoCuL] (.) H2O (.) CH3OH (2) and [(CuL)(2)Ni](.) 2H(2)O (3) have been synthesized and characterized by means of elemental analyses, IR and electronic spectra. The crystal structures of two heterotrinucler complexes were determined by X-ray analysis. Each dissymmetrical cell unit of the complex 2 contains two heterotrinucler neutral molecules. In each neutral molecule, the central CO2+. ion is located at the site Of 06 with a distorted octahedral geometry and one terminal Cu2+ ion at the four-coordination site of N2O2, but the other one at the square-pyramidal environment of N2O3. Each dissymmetrical unit of the complex 3 contains a heterotrinucler neutral molecule, whose structure is similar to that of 2 except two terminal Cu2+ ions both at the inner site of N2O2. The magnetic properties of two heterotrinucler complexes have been determined in the temperature range of 5-300 K, which indicate that the interaction between the central Co2+ ion or Ni2+ ion and the outer Cu2- ions is antiferromagnetic. The exchange integrals are equal to -26.2 cm(-1) for 2 and -50.6 cm(-1) for 3. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.12.032
• 作为产物：
  描述：

  [N-(2-aminoethane)salicylaldiminato]hydroxocopper(II) dihydrate 在 3-carboxylsalicylidene 作用下， 以 乙醇 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Synthesis, characterization, crystal structures and magnetic properties of dissymmetrical double schiff base heterotrinuclear complexes: [CuL(H2O)CoCuL]·H2O·CH3OH and [(CuL)2Ni]·2H2O

  摘要：

  A dissymmetrical double Schiff base Cu(II) mononuclear complex: CuHL (1) (where H3L is N-3-carboxylsalicylidene-N'-saiicylaldehyde- 1,2-diaminoethane) and two trinuclear complexes: [CuL(H2O)CoCuL] (.) H2O (.) CH3OH (2) and [(CuL)(2)Ni](.) 2H(2)O (3) have been synthesized and characterized by means of elemental analyses, IR and electronic spectra. The crystal structures of two heterotrinucler complexes were determined by X-ray analysis. Each dissymmetrical cell unit of the complex 2 contains two heterotrinucler neutral molecules. In each neutral molecule, the central CO2+. ion is located at the site Of 06 with a distorted octahedral geometry and one terminal Cu2+ ion at the four-coordination site of N2O2, but the other one at the square-pyramidal environment of N2O3. Each dissymmetrical unit of the complex 3 contains a heterotrinucler neutral molecule, whose structure is similar to that of 2 except two terminal Cu2+ ions both at the inner site of N2O2. The magnetic properties of two heterotrinucler complexes have been determined in the temperature range of 5-300 K, which indicate that the interaction between the central Co2+ ion or Ni2+ ion and the outer Cu2- ions is antiferromagnetic. The exchange integrals are equal to -26.2 cm(-1) for 2 and -50.6 cm(-1) for 3. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.12.032