[(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate | 241152-08-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate
• 英文别名: [Ru(NC.tplbond.Me)(η(5)-indenyl)(PPh3)2][PF6]；[(η5-indenyl)Ru(PPh3)2(acetonitrile)]PF6；[(η(5)-indenyl)Ru(PPh3)2(CH3CN)]PF6；[Ru(η5-indenyl)(PPh3)2(NCMe)](PF6)；[(η5-indenyl)Ru(PPh3)2(CH3CN)]PF6；[(η5-C9H7)Ru(PPh3)2(CH3CN)]PF6；acetonitrile;1H-inden-1-ide;ruthenium(2+);triphenylphosphane;hexafluorophosphate
• CAS: 241152-08-9
• 化学式: C₄₇H₄₀NP₂Ru*F₆P
• 分子量: 926.823
• InChiKey: GVNQGSCOSPYHHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-acetylpyridine 2,4-dinitrophenylhydrazone 、 [(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate 以 二氯甲烷 、 苯 为溶剂， 以71%的产率得到[(η5-indenyl)Ru(PPh3)(2-pyridylmethyl-2,4-dinitrophenyl ketazine)]PF6
  参考文献：
  名称：

  新单核钌的络合物η 5的合成，光谱和结构研究：-cyclichydrocarbon含有吖嗪配体

  摘要：

  一系列单核茚基五甲基环戊二烯和钌（II）的制剂的配合物[（η 5 -L 3）的Ru（PPH 3）（L 2）] X，（其中L 3  =茚基，五甲基环戊二烯; X = PF 6或BF 4和L 2  =吖嗪配体）已经制备由[（η的反应5 -L 3）的Ru（PPH 3）2（CH 3 CN）] X用甲醇或二氯甲烷/苯混合物中的适当的吖嗪配体。硝基取代的吖嗪配体与复合物反应[（η 5 -L 3 PPH）的Ru（3）2（CH 3 CN）] X取决于溶剂。所有这些复合物均以其PF 6或BF 4盐的形式分离。借助微量分析，FT-IR和NMR光谱对配合物进行了充分表征。代表性配合物5c和6a的分子结构通过单X射线晶体学确定。

  DOI：

  10.1016/j.jorganchem.2005.05.001
• 作为产物：
  描述：

  [Ru(η(5)-indenyl)(PPh3)2=C=C(H)Ph]PF6 、 乙腈 以 乙腈 为溶剂， 以78%的产率得到[(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate
  参考文献：
  名称：

  通过ηA新途径，以官能化的末端炔烃1 -Vinylidene至η 2个-Alkyne互变异构在茚基钌（II）单取代偏二配合物：合成和理论研究

  摘要：

  下的单取代的亚乙烯基复杂的[Ru {的回流溶液加热Ç C（H）PH}（η 5 -C 9 ħ 7）（PPH 3）2 ] [PF 6 ]（1在腈）得到配合物的[Ru（N ⋮CR）（η 5 -C 9 ħ 7）（PPH 3）2 ] [PF 6 ]（R =我（图2a），等（图2b）中，Ph（2C））和苯基乙炔。通过初始η处理前进1 -vinylidene-η 2-炔炔互变异构，然后由溶剂置换配位的π-炔烃。偏二配合物的[Ru { Ç C（H）R}（η 5 -C 9 ħ 7）（PPH 3）2 ] [PF 6 ]（R =（η 5 -C 5 H ^ 4）的Fe（η 5 -C 5 H 5）（3），4-NO 2 -C 6 H 4（4））也与乙腈反应生成腈衍生物2a和相应的末端炔烃HC⋮CR。阳离子烯基-亚乙烯基衍生物[Ru {Ç C（H）CH CR 1 - [R 2 }（η 5 -C 9 ħ 7）（PPH 3）2

  DOI：

  10.1021/om990194v

文献信息

• Unusual activation of 1-ethynyl-1-cyclohexanol by [RuCl(η5-C9H7)(PPh3)2]: synthesis and reactivity of the allenylidene derivative [Ru{CCC(C13H20)}(η5-C9H7)(PPh3)2][PF6]
  作者：Victorio Cadierno、M. Pilar Gamasa、José Gimeno、Elena Lastra

  DOI：10.1039/a904744a

  日期：——

  The reaction of [RuCl(η5-C9H7)(PPh3)2] with an excess of 1-ethynyl-1-cyclohexanol and NaPF6 in refluxing methanol yielded the allenylidene complex [RuCCC(C13H20)}(η5-C9H7)(PPh3)2][PF6] 1 via an unprecedented coupling of two molecules of the propargyl (prop-2-ynyl) alcohol derivative. Complex 1 can also be obtained by reaction of the vinylvinylidene derivative [RuCC(H)R}(η5-C9H7)(PPh3)2][PF6] 2 (R = 1-cyclohexenyl) with 1-ethynyl-1-cyclohexanol or 1-ethynylcyclohexene in refluxing methanol. The behaviour of 2 towards other 1-alkyn-3-ols has been studied but only the replacement of the vinylidene moiety by the propargyl alcohols, via an η1-vinylidene–η2-alkyne tautomerization process, to generate both vinylvinylidene [RuCC(H)R}(η5-C9H7)(PPh3)2][PF6] (R = 1-cyclopentenyl, 1-cycloheptenyl or 1-cyclooctenyl) or allenylidene [Ru(CCCR2)(η5-C9H7)(PPh3)2][PF6] (R = Ph or R2 = 2,2′-biphenyldiyl) complexes along with 1-ethynylcyclohexene was observed. A similar 1,3-enyne elimination also takes place in the reaction of 2 with phenylacetylene or acetonitrile to afford [RuCC(H)Ph}(η5-C9H7)(PPh3)2][PF6] and [Ru(NCMe)(η5-C9H7)(PPh3)2][PF6], respectively. On the basis of these observations a mechanism for the formation of 1 is proposed. The allenylidene complex 1 regioselectively reacts with NaR, in THF at –20 °C, to yield the neutral σ-alkynyl derivatives [RuCCC(C13H20)R}(η5-C9H7)(PPh3)2] (R = CN or OMe). Protonation of the R = CN derivative with HBF4·Et2O, in diethyl ether at –20 °C, afforded the cationic vinylidene complex [RuCC(H)C(C13H20)CN}(η5-C9H7)(PPh3)2][BF4]. In contrast, protonation with R = OMe gives back the starting allenylidene derivative 1.

  [RuCl(η^5-C9H7)(PPh3)2] 与过量的 1-乙炔基-1-环己醇和 NaPF6 在热回流的甲醇中反应，生成了不同寻常的联烯基复合物 [RuCCC(C13H20)}(η^5- )(PPh3)2][PF6] 1，这个反应是由两个丙炔（丙-2-炔基）醇衍生物的分子偶联而成的。复合物 1 也可以通过在热回流的甲醇中，将乙烯-乙烯基衍生物 [RuCC(H)R}(η^5- )(PPh3)2][PF6] 2（R = 1-环己烯基）与 1-乙炔基-1-环己醇或 1-乙炔基环己烯反应获得。已经研究了 2 对其他 1-炔-3-醇的行为，但仅观察到通过 η^1-乙烯基-η^2-炔的互变异构化过程，将乙烯基部分替换为丙炔醇，产生乙烯-乙烯基 [RuCC(H)R}(η^5- )(PPh3)2][PF6]（R = 1-环戊烯基、1-环庚烯基或 1-环辛烯基）或联烯基 [Ru(CCCR2)(η^5- )(PPh3)2][PF6]（R = Ph 或 R2 = 2,2′-联苯基）复合物以及 1-乙炔基环己烯。类似的 1,3-炔烯消除反应也发生在 2 与苯基炔或乙腈的反应中，分别生成 [RuCC(H)Ph}(η^5- )(PPh3)2][PF6] 和 [Ru(NCMe)(η^5- )(PPh3)2][PF6]。基于这些观察，提出了 1 的形成机制。联烯基复合物 1 在 -20 °C 的 THF 中与 NaR 进行区域选择性反应，生成中性的 σ-炔基衍生物 [RuCCC( )R}(η^5- )(PPh3)2]（R = CN 或 OMe）。将 R = CN 的衍生物用 HBF4·Et2O 在 -20 °C 的二乙醚中质子化，生成了阳离子乙烯基复合物 [RuCC(H)C( )CN}(η^5- )(PPh3)2][BF4]。相反，使用 R = OMe 进行质子化则恢复了起始的联烯基衍生物 1。
• Reactivity Studies of η5- Indenyl and η5-Cp* Ruthenium(II) Complexes towards some Polypyridyl Ligands
  作者：Keisham Sarjit Singh、Yurij A. Mozharivskyj、Mohan Rao Kollipara

  DOI：10.1002/zaac.200500301

  日期：2006.1

  of unexpected complexes [Ru(PPh3)2(L2)(CH3CN)][PF6]2; L2 = tppz ([9](PF6)2), tptz ([11](PF6)2) and [Ru(PPh3)2(L2)Cl][PF6]; L2 = tppz ([10]PF6), tptz ([12]PF6). The complexes were isolated as their hexafluorophosphate salts. They have been characterized on the basis of micro analytical and spectroscopic data. The crystal structures of the representative complexes were established by X-ray crystallography

  [(η5-L3)Ru(PPh3)2Cl]的反应，其中；L3 = C9H7 (1)、C5Me5 (Cp *) (2) 在 [NH4] [PF6] 存在下与乙腈生成阳离子络合物 [(η5-L3) Ru (PPh3) 2 (CH3CN)] [PF6]；L3 = ([3] PF6) 和 L3 = C5Me5 ([4] PF6)，分别。配合物 [3] PF6 和 [4] PF6 与一些多吡啶基配体即 2,3-双 (α-吡啶基) 吡嗪 (bpp)、2,3-双 (α-吡啶基) 喹喔啉 (bpq) 反应生成复合物[(η5-L3) Ru (PPh3) (L2)] PF6 其中；L3 = , L2 = bpp, ([5] PF6), L3 = , L2 = bpq, ([6] PF6); L3 = C5Me5, L2 = bpp, ([7] PF6) 和 bpq, ([8] PF6)。然而，[(η5- )
• Synthesis, structural characterization and catalytic activity of indenyl complexes of ruthenium bearing fluorinated phosphine ligands
  作者：Matthew J. Stark、Michael J. Shaw、Arghavan Fadamin、Nigam P. Rath、Eike B. Bauer

  DOI：10.1016/j.jorganchem.2017.03.043

  日期：2017.10

  The synthesis, characterization and catalytic activity of new ruthenium complexes of fluorinated triarylphosphines is described. The new ruthenium complexes [RuCl(ind)(PPh3)P(p-C6H4CF3)3}] and [RuCl(ind)(PPh3)P(3,5-C6H3(CF3)2)3}] were synthesized in 57% and 24% isolated yield, respectively, by thermal ligand exchange of [RuCl(ind)(PPh3)2], where ind = indenyl ligand η5-C9H7−. The electronic and steric

  描述了氟化三芳基膦新钌配合物的合成，表征和催化活性。新的钌络合物[RuCl（ind）（PPh 3）P（p -C 6 H 4 CF 3）3 }]和[RuCl（ind）（PPh 3）P（3,5-C 6 H 3（ CF 3）2）3 }]在分别为57％和24％分离产率，合成，通过将[RuCl（IND）（PPH的热交换配位体3）2 ]，其中的ind =茚基配位体η 5 -C 9 ħ 7 -。通过分析X射线结构和循环伏安法研究了新配合物的电子和空间特性。新的络合物[RuCl（ind）（PPh 3）P（p -C 6 H 4 CF 3）3 }]和[RuCl（ind）（PPh 3）P（3,5-C 6 H 3（CF 3）2）3 }]和已知的络合物[RuCl（ind）（PPh 3）2}]从键合长度和与钌中心相关的角度的比较中可以看出，它们的空间性质仅略有不同。通过循环伏安法测定，[RuCl（ind）（PPh
• Synthesis and characterization of [(Cp*)Ru(PPh3)(N-base)]X and [(η5-C9H7)Ru(PPh3)(N-base)]X complexes: crystal and molecular structure of the complex [(η5-C9H7)Ru(PPh3)(phen)]PF6
  作者：Kollipara Mohan Rao、Evergreen K. Rymmai

  DOI：10.1016/s0277-5387(02)01335-9

  日期：2003.1

  The reactions of [(eta(5)-Cp*)Ru(PPh3)(2)(CH3CN)]X (1) and [(eta(5)-indenyl)Ru(PPh3)(2)(CH3CN)]X (2) (eta(5)-CP* = eta(5)-C5Me5; eta(5)-indenyl = eta(5) -C9H7; X = BF4 or PF6) with 2,2'-bipyridine (bipy.) and 1,10-phenanthroline (phen.) in benzene or toluene yielded complexes of the type [(eta(5)-Cp*)Ru(PPh3)(L-2)]X where L-2 = bipy, X = BF4 (3) and L-2 = phen, X = PF6 (4); [(eta(5)-indenyl)Ru(PPh3)(2)(L-2)]X where L2 = bipy, X = PF6 (5) and L2 = phen, X = PF6 (6). Complex 6 has been established by single crystal X-ray diffraction analysis. Complex 6 crystallizes in the monoclinic space group P 21/c, with a = 14.6020 (12), b = 12.7100 (17) and c = 18.981 (2) Angstrom, beta = 98.982 (9)degrees, V = 3479.5 (7) Angstrom(3) and Z = 4. These complexes can also be prepared from reactions Of [(eta(5)- Cp*)Ru(PPh3)(2)Cl] (7) and [(eta(5)-indenyl)Ru(PPh3)(2)Cl] (8) with the corresponding ligands in the presence of NH4PF6 or NH4BF4 in toluene. All the complexes were characterized by spectral and analytical data. (C) 2002 Elsevier Science Ltd. All rights reserved.
• Rymmai; Rao, K. Mohan, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2003, vol. 42, # 8, p. 1892 - 1895
  作者：Rymmai、Rao, K. Mohan

  DOI：——

  日期：——