o-tert.Butylphenyl-acrylat | 22440-67-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: o-tert.Butylphenyl-acrylat
• 英文别名: (2-Tert-butylphenyl) prop-2-enoate
• CAS: 22440-67-1
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.269
• InChiKey: VHRJYXSVRKBCEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  o-tert.Butylphenyl-acrylat 、 三苯基硅烷 在 iron(III) chloride 、 lithium chloride 作用下， 以 乙腈 为溶剂， 反应 20.0h， 以44%的产率得到
  参考文献：
  名称：

  铁催化缺电子烯烃的可见光诱导氢化硅烷化

  摘要：

  Lights ON：开发了一种铁催化、可见光诱导的缺电子烯烃氢化硅烷化反应的方法。氯自由基作为氢原子转移试剂产生甲硅烷基自由基。自由基与烯烃底物反应形成 Si-C 键。该方法的原子经济性和含硅产物的可控性可用于含硅化合物的合成和转化。

  DOI：

  10.1002/cssc.202200367

文献信息

• [EN] PYRAZINE AND IMIDAZOLIDINE DERIVATIVES AND THEIR USES TO TREAT HEPATITIS C<br/>[FR] DÉRIVÉS DE PYRAZINE ET D'IMIDAZOLIDINE ET LEURS UTILISATIONS EN VUE DU TRAITEMENT DE L'HÉPATITE C
  申请人：GILEAD PHARMASSET LLC

  公开号：WO2012103113A1

  公开（公告）日：2012-08-02

  Disclosed herein are compounds useful for treating a viral infection, such HCV.

  本文披露了一些用于治疗病毒感染，如HCV的化合物。
• Semiconductor wafer processing tapes
  申请人：3M Innovative Properties Company

  公开号：US20010016257A1

  公开（公告）日：2001-08-23

  A semiconductor wafer processing tape includes a permanent backing and a layer of a nonpressure sensitive adhesive. The tapes are useful for wafer grinding and/or wafer dicing applications. The nonpressure sensitive adhesive includes a copolymer of at least one of a first monoethylenically unsaturated monomer, at least one of a second monoethylenically unsaturated monomer, and at least one copolymerizable nonionic crosslinking agent; wherein the second monoethylenically unsaturated monomer is a reinforcing monomer having a homopolymer glass transition temperature higher than that of the first monoethylenically unsaturated monomer. A method of processing semiconductor wafers is also provided.

  一种半导体晶片加工胶带，包括一个永久的背衬和一层非压敏粘合剂。该胶带适用于晶片研磨和/或晶片切割应用。非压敏粘合剂包括至少一种第一单乙烯不饱和单体，至少一种第二单乙烯不饱和单体和至少一种可共聚的非离子交联剂的共聚物；其中第二单乙烯不饱和单体是一种增强单体，其均聚物玻璃化转变温度高于第一单乙烯不饱和单体的玻璃化转变温度。还提供了一种半导体晶片加工方法。
• Fluorine-containing graft copolymer and adhesive and composite membrane made thereof
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0183989A2

  公开（公告）日：1986-06-11

  A graft copolymer consisting essentially of a main chain polymer having a glass transition temperature (Tg) of at least 30°C and a graft chain fluorine-containing polymer having a repeating unit of the formula: wherein R1 is a hydrogen atom or a lower alkyl group, and R2 is a polyfluoroalkyl group.

  一种接枝共聚物，主要由玻璃化转变温度（Tg）至少为 30°C 的主链聚合物和具有以下重复单元的接枝链含氟聚合物组成： 其中 R1 为氢原子或低级烷基，R2 为多氟烷基。
• One-piece intraocular lenses
  申请人：Menicon Co., Ltd.

  公开号：EP0461604A2

  公开（公告）日：1991-12-18

  A material for one-piece intraocular lenses consisting essentially of a copolymer of which main components are methyl methacrylate and at least one (meth)acrylate selected from an alkyl acrylate having a glass transition temperature of higher than 30°C and up to 100°C and a fluoroalkyl (meth)acrylate having a glass transition temperature of higher than 30°C and up to 100°C is disclosed. The material for one-piece intraocular lenses is excellent in cutting-processability, grindability, machinability and suitable flexibility, and can be suitably used for not only one-piece intraocular lenses but also three-piece intraocular lenses.

  本发明公开了一种用于单片眼内透镜的材料，该材料主要由一种共聚物组成，其主要成分是甲基丙烯酸甲酯和至少一种（甲基）丙烯酸酯，该共聚物选自玻璃化转变温度高于 30°C 但不超过 100°C 的丙烯酸烷基酯和玻璃化转变温度高于 30°C 但不超过 100°C 的（甲基）丙烯酸氟烷基酯。这种用于单片眼内透镜的材料在切削加工性、研磨性、机加工性和适当的柔韧性方面都非常出色，不仅可用于单片眼内透镜，还可用于三片眼内透镜。
• Polyolefin resin composition and oriented film therefrom
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0791625A2

  公开（公告）日：1997-08-27

  A polyolefin resin composition comprising: (a) 100 parts by weight of a polyolefin resin; and (b) 0.05 to 1 part by weight of beads of a crosslinked polymer comprising (1) 5 to 99% by weight of a radically polymerizable monomer unit of formula (A): wherein R1 is hydrogen or a hydrocarbon group having 1 to 5 carbon atoms and R2 is a hydrocarbon group having 5 to 30 carbon atoms, (2) 0 to 94% by weight of a radically polymerizable monomer unit other than the monomer unit of formula (A), and (3) 1 to 20% by weight of a crosslinkable monomer unit, the percentages being measured relative to the total weight of components (1), (2) and (3), said crosslinked polymer beads having a critical surface tension of 40 dyne/cm or less.

  一种聚烯烃树脂组合物，包括：(a)100 重量份的聚烯烃树脂；和(b)0.05 至 1 重量份的交联聚合物微珠，其中包括(1)5 至 99%重量份的式(A)可辐射聚合单体单元： 其中 R1 是氢或具有 1 至 5 个碳原子的烃基，R2 是具有 5 至 30 个碳原子的烃基；(2) 0 至 94%(重量)的式(A)单体单元以外的可辐射聚合单体单元；(3) 1 至 20%(重量)的可交联单体单元，这些百分比是相对于组分(1)、(2)和(3)的总重量而言的，所述交联聚合物珠的临界表面张力为 40 达因/厘米或更小。