| 188396-91-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 188396-91-0
• 化学式: C₃₂H₃₀AgN₄*ClO₄
• 分子量: 677.936
• InChiKey: WLAKQEUMVVIDGN-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  1,4-(5'-methyl-2,2'-bipyridine-5-ethyl)benzene 、 lithium perchlorate 、 silver nitrate 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  X-ray crystal structure of copper(II) and silver(I) complexes with the new ligand 1,4-bis(5′-methyl-2,2′-bipyridine-5-ethyl)-benzene: the effects of substituent and linking position on the assembly of helical complexes

  摘要：

  A new tetradentate ligand 1,4-bis(5'-methyl-2,2'-bipyridine-5-ethyl)-benzene(p-bpy) and its Cu-II and Ag-I complexes were synthesized. In complex 1, Cu(p-bpy)[ClO4](2) . 0.5MeCN, the four nitrogen atoms of the ligand coordinate with one Cu-II to form a flattened tetrahedron. The metal ion also has weak interactions with two ClO4- ions, which link the Cu-II ions in a one dimensional fashion to make an infinite chain. In complex 2, Ag(p-bpy)[ClO4], the coordination geometry of Ag-I is flattened tetrahedron. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00426-3