pentamethylcyclopentadienyliridium(III) methyl PMe3 (CD2Cl2)[CH3B(C6F5)3] | 351318-34-8

• 英文名称: pentamethylcyclopentadienyliridium(III) methyl PMe3 (CD2Cl2)[CH3B(C6F5)3]
• CAS: 351318-34-8
• 化学式: C₁₅H₂₉Cl₂IrP*C₁₉H₃BF₁₅
• 分子量: 1032.5
• InChiKey: FBRMJWARKKWDHH-QBAMQYMWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η5-C5Me5)(PMe3)Ir(CH3)2 、 二氯甲烷-D2 、 三(五氟苯基)硼烷 以 二氯甲烷-D2 为溶剂， 以98%的产率得到pentamethylcyclopentadienyliridium(III) methyl PMe3 (CD2Cl2)[CH3B(C6F5)3]
  参考文献：
  名称：

  Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solution

  摘要：

  This report details our work in the area of C-H activation by cationic Ir(III) complexes. We highlight the previously reported chemistry of transition metal complexes of the type Cp-*(PMe3)Ir(R)(X) (Cp-* is pentamethylcyclopentadienyl or eta(5) -C5Me5; R = alkyl, hydrido; X = OSO2CF3, B(3,5-(CF3)(2)C6H3)(4))), and disclose new results concerning the production of these complexes using Lewis acids (LAs). Additionally, new work aimed at examining the mechanism of C-H activation by these complexes is presented. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(02)00192-9