| 741706-28-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• CAS: 741706-28-5
• 化学式: C₄₆H₅₆N₄O₂
• 分子量: 696.976
• InChiKey: DUKYYHSADWSTBT-BXJOYJMKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.88
• 重原子数：
  52.0
• 可旋转键数：
  0.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  67.9
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Light-Driven Molecular Hinge:  A New Molecular Machine Showing a Light-Intensity-Dependent Photoresponse that Utilizes the Trans−Cis Isomerization of Azobenzene

  摘要：

  A new class of molecular machine exhibits a hingelike motion upon photo irradiation. The motion (close and open) can be operated by alternate irradiation with UV and visible light. The trans/trans and cis/cis isomers are thermally stable at 40degreesC, and the photochemical closure reaction (from trans/trans to cis/cis isomer) is dependent on the intensity of the light used because of the short-lived intermediate (trans/cis isomer).

  DOI：

  10.1021/ol049082c
• 作为产物：
  描述：

  2,7-di-tert-butyl-9,9-dimethyl-9H-xanthene-4,5-diamine 在 manganese(IV) oxide 、 potassium tert-butylate 、 氧气 作用下， 以 二甲基亚砜 、 叔丁醇 、 苯 为溶剂， 反应 88.0h， 生成
  参考文献：
  名称：

  Light-Driven Molecular Hinge:  A New Molecular Machine Showing a Light-Intensity-Dependent Photoresponse that Utilizes the Trans−Cis Isomerization of Azobenzene

  摘要：

  A new class of molecular machine exhibits a hingelike motion upon photo irradiation. The motion (close and open) can be operated by alternate irradiation with UV and visible light. The trans/trans and cis/cis isomers are thermally stable at 40degreesC, and the photochemical closure reaction (from trans/trans to cis/cis isomer) is dependent on the intensity of the light used because of the short-lived intermediate (trans/cis isomer).

  DOI：

  10.1021/ol049082c