(aniline)(3-cyanopropyl)bis(dimethylglyoximato)cobalt(III) | 391249-96-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (aniline)(3-cyanopropyl)bis(dimethylglyoximato)cobalt(III)
• CAS: 391249-96-0
• 化学式: C₁₈H₂₇CoN₆O₄
• 分子量: 450.443
• InChiKey: JBYVVZHASQCEGR-DVTASQICSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (aniline)(3-cyanopropyl)bis(dimethylglyoximato)cobalt(III) 以 solid 为溶剂， 生成 aniline-1-cyanopropylcobaloxime
  参考文献：
  名称：

  通过 2-取代的丙基配合物将 3-取代的丙基固态特异性和单向光异构化为 1-取代的丙基钴肟配合物

  摘要：

  发现 3-氰丙基和 3-（甲氧基羰基）丙基钴肟配合物的固态特异性（γ→β→α）光异构化发生在可见光照射下。反应速率存在相当大的差异，这与轴向配体的碱度无关。在前一系列复合物中，第二步（β→α）的速率常数（k2）比第一步的（k1）快得多。然而，在后面的一系列络合物中，第二步的速率常数（k2）趋向于极度降低，因此，k2变得小于k1。

  DOI：

  10.1246/cl.2001.1190

文献信息

• Solid state-specific and chiral lattice-controlled asymmetric photoisomerization of 3-substituted propyl cobalt complexes, and direct observation of the intermediate complex
  作者：Yoshiaki Ohgo、Kanako Ishida、Yoshito Hiraga、Yoshifusa Arai、Seiji Takeuchi

  DOI：10.1016/j.jorganchem.2005.12.067

  日期：2006.5

  Solid state-specific and chiral lattice-controlled asymmetric photoisornerization of 3-cyanopropyl cobaloxime complexes coordinated with chiral axial ligand. la-h. was found to occur with moderate to relatively high enantioselectivities (similar to 91%ee), even though the reaction proceeds through radical species. The enantioselectivities at a lower temperature (-78 degrees C) are extremely enhanced as compared to those at room temperature. in most cases.The configuration of the major enantiomer of the isomerized product is predictable from the shape of the reaction cavity, drawn based on the crystal structure of the starting material. The structure (including absolute configuration) of the intermediate 2-cyanopropyl complex was directly observed by X-ray crystallographic analyses of a single-crystal-to-single-crystal reaction of (S)-1-cyclohexylethylamine-coordinated 3-cyanopropyl cobaloxime, 1e. (c) 2006 Elsevier B.V. All rights reserved.