trans-RuCl2((1,4-diphenylphosphino)butane)2(4-methylpyridine)2 | 200259-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-RuCl2((1,4-diphenylphosphino)butane)2(4-methylpyridine)2
• CAS: 200259-41-2
• 化学式: C₄₀H₄₂Cl₂N₂P₂Ru
• 分子量: 784.71
• InChiKey: XIQAPOOSGZVMFV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  4-甲基吡啶 、 {RuCl2(dppb)}2(μ-dppb) 以 二氯甲烷 为溶剂， 以77%的产率得到trans-RuCl2((1,4-diphenylphosphino)butane)2(4-methylpyridine)2
  参考文献：
  名称：

  Queiroz, Salete L.; Batista, Alzir A.; Oliva, Glaucius, Inorganica Chimica Acta, 1998, vol. 267, # 2, p. 209 - 221

  摘要：

  DOI：

文献信息

• Electrosynthesis of binuclear ruthenium complexes from [RuCl3(dppb)(L)] precursors [L = pyridine, 4-methylpyridine or dimethyl sulfoxide; dppb = 1,4-bis(diphenylphosphino)butane]
  作者：Karen Wohnrath、Márcio Peres de Araujo、Luis Rogério Dinelli、Alzir Azevedo Batista、Icaro de Sousa Moreira、Eduardo Ernesto Castellano、Javier Ellena

  DOI：10.1039/b001422m

  日期：——

  Electrolysis has been examined as a method of synthesis for [(L)(dppb)Ru(μ-Cl)3RuCl(dppb)] complexes, where dppb = 1,4-bis(diphenylphosphino)butane and L = pyridine (py), 4-methylpyridine (4-pic) or dimethyl sulfoxide (DMSO), by using [RuCl3(dppb)(L)] as precursors. The products of the electrolysis were characterized by 31P-1H} NMR, cyclic voltammetry and near infrared spectroscopy. The presence of the [Ru2Cl5(dppb)2] complex in the electrochemical cell suggests a mechanism by which the starting original species from the bulk solution reacts with the reduced form [RuCl2(dppb)(L)] generated at the surface of the electrode. The crystal structure of the precursor mer-[RuCl3(dppb)(4-pic)] was determined by X-ray diffraction.