[Ag(NO2)(3,3'-oxybispyridine)] | 610310-90-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ag(NO2)(3,3'-oxybispyridine)]
• CAS: 610310-90-2
• 化学式: C₁₀H₈AgN₃O₃
• 分子量: 326.06
• InChiKey: ZTEYOHIAOVFIPO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ag(3,3'-oxybispyridine)]NO3 、 sodium nitrite 以 水 为溶剂， 生成 [Ag(NO2)(3,3'-oxybispyridine)]
  参考文献：
  名称：

  Chelating ability and role of nitrite. Synthesis and structural properties of AgNO2 with 3,3′-oxybispyridine

  摘要：

  The reaction of silver(I) nitrite with 3,3'-oxybispyridine (Py2O) produces a coordination polymer of [Ag(NO2)Py2O] unit. The Py2O ligand connects two Ag(I) ions via the nitrogen donors of 3-pyridyl group to give a zigzag single strand. The nitrite anion acts as a chelating ligand rather than a counteranion. Thus, the Ag(I) ion is surrounded by N2O2 donors including the chelating nitrite. Thermal properties and anion exchange are consistent with the structural features such as the chelating ability of NO2- and the relatively weak bonds of Ag-N. The chelating ability of anion has a significant effect on the formation of skeletal structure in coordination polymerization. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00369-7