diallylguanidin acetate | 42072-36-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: diallylguanidin acetate
• 英文别名: N,N-diallylguanidine acetate；1,1-Diallyl-guanidin-acetat；Diallylguanidinium acetate；diaminomethylidene-bis(prop-2-enyl)azanium;acetate
• CAS: 42072-36-6
• 化学式: C₂H₄O₂*C₇H₁₃N₃
• 分子量: 199.253
• InChiKey: KWWFZKXVMQRLQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.64
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  95.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  diallylguanidin acetate 在 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 13.5h， 以100%的产率得到diallylguanidin
  参考文献：
  名称：

  Macromolecular design of new cationic polyelectrolytes

  摘要：

  Methods were elaborated for the synthesis of new monomers, derivatives of diallylguanidine and macromers, which contain fragments of polytetrahydrofuran and diallylic nitrogen-containing end groups (diallylamine, alkyldiallylammonium, diallylguanidine both in base and acetate forms). Alkylation of a macromer with a diallylamine end group was carried out with methyl iodide in various organic solvents. The possibility of synthesis of diallylguanidine acetate homopolymer as well as its statistical copolymer with diallyldimethylammonium chloride was shown. For the first time, block copolymers based on synthesized macromers were obtained.

  DOI：

  10.1007/bf00696318
• 作为产物：
  描述：

  氰胺 、 diallylammonium acetate 以 乙腈 为溶剂， 反应 3.5h， 以73%的产率得到diallylguanidin acetate
  参考文献：
  名称：

  Macromolecular design of new cationic polyelectrolytes

  摘要：

  Methods were elaborated for the synthesis of new monomers, derivatives of diallylguanidine and macromers, which contain fragments of polytetrahydrofuran and diallylic nitrogen-containing end groups (diallylamine, alkyldiallylammonium, diallylguanidine both in base and acetate forms). Alkylation of a macromer with a diallylamine end group was carried out with methyl iodide in various organic solvents. The possibility of synthesis of diallylguanidine acetate homopolymer as well as its statistical copolymer with diallyldimethylammonium chloride was shown. For the first time, block copolymers based on synthesized macromers were obtained.

  DOI：

  10.1007/bf00696318