(2-Ethyl-hexyl)-vinyl-sulfid | 85996-76-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (2-Ethyl-hexyl)-vinyl-sulfid
• 英文别名: Vinyl-(2-ethyl-hexyl)-sulfid；(2-ethyl-hexylsulfanyl)-ethene；3-(Ethenylsulfanylmethyl)heptane
• CAS: 85996-76-5
• 化学式: C₁₀H₂₀S
• 分子量: 172.335
• InChiKey: SHACZUNWUKZSDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Thermosetting compositions, thermal latent hydroxyl compounds, thermal latent thiol compounds and methods of preparation thereof
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0452841A2

  公开（公告）日：1991-10-23

  Thermosetting compositions are excellent in storage stability, useful as one component thermosetting compositions, give cured products having excellent chemical properties, physical properties and weathering resistance and favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting compositions comprise a compound having in the molecule two or more hydroxyl groups and/or thiol groups blocked by a vinyl ether compound, a vinyl thioether compound or a heterocyclic compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked hydroxyl and/or thiol compound by heating and a thermal latent acid catalyst. The blocked hydroxyl and/or thiol group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

  热固性组合物具有优异的储存稳定性，可用作单组分热固性组合物，固化后的产品具有优异的化学性质、物理性质和耐候性，可用于涂料组合物、油墨、粘合剂和模塑塑料。 热固性组合物包括一种化合物，其分子中的两个或两个以上羟基和/或硫醇基团被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基双键并以氧或硫作为杂原子的杂环化合物阻断；一种化合物，其分子中的两个或两个以上活性官能团可通过加热与被阻断的羟基和/或硫醇化合物形成化学键；以及一种热潜伏酸催化剂。第一种化合物的受阻羟基和/或硫醇基团与第二种化合物的活性官能团可包含在同一分子中。
• Thermosetting compositions, thermal latent carboxyl compounds and methods of preparation thereof
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0451738A2

  公开（公告）日：1991-10-16

  Thermosetting composition is excellent in storage stability, is useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

  热固性组合物具有出色的储存稳定性，可用作单组分热固性组合物，固化后的产品具有出色的化学性质、物理性质和耐候性，可用于涂料组合物、油墨、粘合剂和模塑塑料。 这种热固性组合物包括一种化合物，其分子中有两个或两个以上的羧基被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基双键且氧或硫为杂原子的杂化合物封住；一种化合物，其分子中有两个或两个以上的活性官能团，通过加热可与被封住的羧基化合物形成化学键；还可选择使用一种热潜伏酸催化剂。第一种化合物的封端羧基和第二种化合物的活性官能团可以包含在同一个分子中。
• Thermosetting compositions, thermal latent acid catalysts, method of coating and coated articles
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0535667A2

  公开（公告）日：1993-04-07

  Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.

  热固性组合物包括：分子中具有两个或两个以上被乙烯基醚化合物、乙烯基硫醚化合物或具有乙烯基型双键且氧或硫为杂原子的杂化合物封端的羧基的化合物；具有两个或两个以上可通过加热与被封端的羧基化合物形成化学键的活性官能团的化合物；特定的乙烯基醚或乙烯基硫醚和热潜酸催化剂。第一种化合物的封端羧基和第二种化合物的活性官能团可以包含在同一个分子中。热固性组合物固化后的产品具有优异的化学性质、物理性质、耐候性和储存稳定性，可用于涂料组合物、油墨、粘合剂和模塑塑料。
• Curable composition, thermal latent acid catalyst, method of coating, coated article, method of molding and molded article
  申请人：NOF CORPORATION

  公开号：EP0643112A2

  公开（公告）日：1995-03-15

  57 A curable composition comprising (A) a compound having in the molecule two or more specific blocked carboxyl groups; (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a catalitic component selected from the group sonsisting of a thermal latent acid catalyst which comprises (a) (i) a compound having a epoxy group, (ii) a specific compound having a sulfur atom and (iii) a specific Lewis acid; a thermal latent acid catalyst which comprises (b) (v) a specific compound having at least one selected from the group consisting of a nitrogen atom, an oxygen atom, a phosphorus atom and a sulfur atom, (vi) a specific compound having a halogen atom and (vii) a specific Lewis acid having at least one selected from the group consisting of an aluminium atom, a zinc atom and a tin atom; and a mixture which comprises (c) (viii) a metallic chelate compound and (ix) a specific organic silicon compound or the condensate. A two component curable composition is prepared by mixing (I) a main material composition or a solution thereof comprising the compound (A) and the compound (B) or the self-crosslinkable compound (D), and (II) an acid catalyst or the solution comprising at least one kind selected from the group consisting of a Br q) nsted acid, a Lewis acid and a mixture of a metallic chelate compound and a compound having a silanol group.The curable composition of the invention gives cured products having excellent chemical properties, physical properties, weathering resistance, stain resistance and excellent appearance.

  57 一种可固化组合物，包括(A)分子中具有两个或两个以上特定封端羧基的化合物；(B)分子中具有两个或两个以上可与封端羧基形成化学键的活性官能团的化合物，以及(C)选自以下组别的催化组分：热潜酸催化剂，包括(a)(i)具有环氧基团的化合物，(ii)具有硫原子的特定化合物和(iii)特定路易斯酸；一种热潜伏酸催化剂，它包括(b)(v)一种特定化合物，其中至少有一种选自氮原子、氧原子、磷原子和硫原子组成的组，(vi)一种特定化合物，其中至少有一种选自卤素原子，(vii)一种特定路易斯酸，其中至少有一种选自铝原子、锌原子和锡原子组成的组；以及一种混合物，它包括(c)(viii)一种金属螯合物和(ix)一种特定有机硅化合物或其缩合物。双组分可固化组合物的制备方法是将(I)主材料组合物或其溶液（包括化合物(A)和化合物(B)或自交联化合物(D)）和(II)酸催化剂或溶液（包括至少一种选自 Br q) nsted 酸、路易斯酸和金属螯合物与具有硅烷醇基的化合物的混合物）混合在一起。
• Curable base-coat composition, method of film-forming and coated articles
  申请人：NOF CORPORATION

  公开号：EP0709415A2

  公开（公告）日：1996-05-01

  A curable base-coat composition which comprises (1) a resin component essentially consisting of a polymer of an ethylenically unsaturated monomer having 500 to 4,000 of an epoxy equivalent, 10 to 200 of a hydroxyl value, ―30 to 80°C of a glass transition temperature and 3,000 to 150,000 of a weight average molecular weight, (2) a curing agent having two or more functional groups in the molecular which can react with the hydroxyl groups of the resin component (1), (3) a Lewis acid catalyst, and (4) a pigment selected from the group consisting of a color pigment and a bright pigment. The curable base-coat composition has adhesive active points to curable clear-coat compositions comprising the acid curing agents blocked chemically and the resins containing epoxy groups or curable clear-coat compositions of the polyol-melamine type and/or the polyol-melamine-polyisocyanate type and gives a cured film having excellent cured film properties. The curable base-coat composition sufficiently exert the excellent characteristics of curable clear-coat compositions.

  一种可固化的底层涂料组合物，它包括：(1) 一种树脂组分，主要由乙烯不饱和单体的聚合物组成，其环氧当量为 500 至 4000，羟基值为 10 至 200，玻璃化温度为-30 至 80°C，重量平均分子量为 3000 至 150、(2) 一种固化剂，其分子中含有两个或两个以上可与树脂组分 (1) 的羟基反应的官能团；(3) 一种路易斯酸催化剂；以及 (4) 一种颜料，选自彩色颜料和亮光颜料组成的组。这种可固化基涂层组合物对由化学封锁的酸固化剂和含有环氧基团的树脂组成的可固化清漆组合物或多元醇-三聚氰胺型和/或多元醇-三聚氰胺-多异氰酸酯型可固化清漆组合物具有粘合活性点，并能生成具有优异固化膜性能的固化膜。可固化基涂层组合物充分发挥了可固化透明涂层组合物的优异特性。