[Cu(N,N'-bis(pyrazol-3-ylmethyl)-1,2-ethanediamine)(NO3)]Cl | 202330-26-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: [Cu(N,N'-bis(pyrazol-3-ylmethyl)-1,2-ethanediamine)(NO3)]Cl
• CAS: 202330-26-5
• 化学式: C₁₀H₁₆CuN₇O₃*Cl
• 分子量: 381.281
• InChiKey: NBYHZIBGKVBQPD-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 在 K₂CO₃ or Na₂CO₃ 作用下， 以 甲醇 为溶剂， 以46%的产率得到[Cu(N,N'-bis(pyrazol-3-ylmethyl)-1,2-ethanediamine)(NO3)]Cl
  参考文献：
  名称：

  Copper(II) complexes of pyrazol-3-yl amines. Synthesis, crystal and solution structure

  摘要：

  The new ligand N,N'-bis(pyrazol-3-ylmethyl)-1,2-ethanediamine (L) was prepared. Reaction with copper(II) salts afforded the complexes [(L)Cu(NO3)]Cl (1) and {[(L)Cu(ClO4)](2)[(pzen-H)(2)Cu-2(ClO4)(2)]}(ClO4)(2) (3) which were characterized by X-ray crystallography. The latter complex was obtained in low yield from a crude sample of L which contained N-(pyrazol-3-ylmethyl)-1,2-ethanediamine (pzen) as an impurity. In the [(L)Cu(X)](+) cations square-pyramidal copper(II) is in-plane coordinated by tetradentate L, with the anion X in the apical position. The copper ions in dinuclear [(pzen-H)(2)Cu-2(ClO4)(2)] are bis(pyrazolate) bridged. In aqueous solution [(L)Cu](2+) is in pH-dependent equilibrium with a dimeric species. By precipitation with NaClO4 both monomeric [(L)Cu(ClO4)(2)] (2) and dimeric [(L-H)(2)Cu-2(ClO4)(2) (4) were isolable at pH 4.5 and pH 8.5, respectively. Based on spectroscopical and analytical data we suggest that 4 is a bis(pyrazolate) bridged complex in solution and in the solid state. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05777-0