cis-[(C2H5O)2dinitrosylchromium] | 253275-77-3

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 炔丙基型1，3-偶极有机化合物
• 英文名称: cis-[(C2H5O)2dinitrosylchromium]
• CAS: 253275-77-3
• 化学式: C₄H₁₀CrN₂O₄
• 分子量: 202.13
• InChiKey: NEYVMNNEHVFPDD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tin(ll) chloride 、 cis-[(C2H5O)2dinitrosylchromium] 以 二氯甲烷 为溶剂， 生成 cis-[(C2H5O)2dinitrosylchromium(SnCl4)]n
  参考文献：
  名称：

  Structure and chemical bonding in cis- and trans-M(NO)2(O2CR)2 (M=Cr and Mo) complexes

  摘要：

  New cis- and trans-nitrosyl complexes of the formula M(NO)(2)(O2CR)(2) (M = Cr and Mo) were synthesized and characterized spectroscopically. The supporting theoretical studies indicate the deviation of molecules from their ideal geometries. The most striking consequence is the deformation of the ON-M-NO fragment from its linear form: in trans complexes. This deformation leads to the additional weak v(s)(NO) vibration. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00556-8
• 作为产物：
  描述：

  trans-[(C2H5O)2dinitrosylchromium] 以 甲苯 为溶剂， 生成 cis-[(C2H5O)2dinitrosylchromium]
  参考文献：
  名称：

  Structure and chemical bonding in cis- and trans-M(NO)2(O2CR)2 (M=Cr and Mo) complexes

  摘要：

  New cis- and trans-nitrosyl complexes of the formula M(NO)(2)(O2CR)(2) (M = Cr and Mo) were synthesized and characterized spectroscopically. The supporting theoretical studies indicate the deviation of molecules from their ideal geometries. The most striking consequence is the deformation of the ON-M-NO fragment from its linear form: in trans complexes. This deformation leads to the additional weak v(s)(NO) vibration. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00556-8