palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dichloride | 308320-51-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dichloride
• CAS: 308320-51-6
• 化学式: C₅₂H₄₈Cl₂P₄PdS₂
• 分子量: 1038.31
• InChiKey: REDUDEDBCUFWBC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  11.88
• 重原子数：
  61.0
• 可旋转键数：
  16.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dichloride 以 氯仿 、 乙腈 为溶剂， 生成 palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dinitrate
  参考文献：
  名称：

  P,S-Ligands. Complexes ofP,P,P′,P′-tetraphenylethylenediphosphine monosulfide with PdCl2

  摘要：

  1 : 1 and 1 : 2 complexes of Ph2P(CH2)(2)P(S)Ph-2 with PdCl2 were synthesized. Their structures were established by P-31 NMR and IR spectroscopy and X-ray diffraction analysis. In the crystals, the 1 : 1 complex has a chelate structure. In CH2Cl2, this complex partially dissociates at the Pd ... S=P bond. According to the X-ray diffraction data, only the P-III atoms in the 1 : 2 complex are coordinated. The reaction of the I : 2 complex with AgNO3 afforded the cationic chelate complex [Pd(Ph2P(CH2)(2)P(S)Ph-2)(2)](2+) 2NO(3)(-).

  DOI：

  10.1007/bf02494907
• 作为产物：
  描述：

  palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dichloride, solvate with chloroform 以 neat (no solvent, solid phase) 为溶剂， 生成 palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dichloride
  参考文献：
  名称：

  P,S-Ligands. Complexes ofP,P,P′,P′-tetraphenylethylenediphosphine monosulfide with PdCl2

  摘要：

  1 : 1 and 1 : 2 complexes of Ph2P(CH2)(2)P(S)Ph-2 with PdCl2 were synthesized. Their structures were established by P-31 NMR and IR spectroscopy and X-ray diffraction analysis. In the crystals, the 1 : 1 complex has a chelate structure. In CH2Cl2, this complex partially dissociates at the Pd ... S=P bond. According to the X-ray diffraction data, only the P-III atoms in the 1 : 2 complex are coordinated. The reaction of the I : 2 complex with AgNO3 afforded the cationic chelate complex [Pd(Ph2P(CH2)(2)P(S)Ph-2)(2)](2+) 2NO(3)(-).

  DOI：

  10.1007/bf02494907