| 1010687-81-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1010687-81-6
• 化学式: C₄₆H₆₀CoN₂O₂
• 分子量: 731.988
• InChiKey: PGSCURIMRDKXNG-VTRQUILJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) diacetate tetrahydrate 、 N-(3-tert-butylsalicylidene)-2',6'-diisopropylaniline 在 NaOH 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  The catalytic oxidation of phenol in aqueous media using cobalt(II) complexes derived from N-(aryl) salicylaldimines

  摘要：

  The synthesis of tetradentate cobalt(II) salicylaldiminato complexes and their catalytic evaluation in the oxidation of phenol is reported. Tetradentate cobalt complexes [Co(L-n)(2)] were obtained by reacting the N-(aryl)salicylaldimine ligands (HL1-HL6) with cobalt acetate in a 2:1 mole ratio. All complexes were characterized using FT-IR and elemental analysis. X-ray crystal structures of complexes 1, 2 and 5 have also been obtained. All complexes were found to be active for the oxidation process. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.10.031