(PPh3)2PtH[C-HC(SO2CF3)2] | 99880-91-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (PPh3)2PtH[C-HC(SO2CF3)2]
• CAS: 99880-91-8
• 化学式: C₃₉H₃₂F₆O₄P₂PtS₂
• 分子量: 999.831
• InChiKey: SNYAIHXFPPJJFI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (PPh3)2PtH[C-HC(SO2CF3)2] 、 、 乙腈 以 乙腈 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Solid-state chemistry of molecular metal oxide clusters. Synthesis and lattice mobility of coordinatively unsaturated platinum cations in a microporous solid

  摘要：

  Metathetic reactions of (R3P)(2)PtH(CH3CN)(+) and PW12O403- yield [(R3P)(2)PtH(CH3CN)](3)PW12O40 (R = Ph, Et). Thermal desolvation of solid [(Ph3P)(2)PtH(CH3CN)](3)PW12O40 yields [(Ph3P)(2)PtH](3)PW12O40 which is thought to contain interstitial (Ph3P)(2)PtH+ ions, Quantitative loss of acetonitrile from [(Et3P)(2)PtH(CH3CN)](3)PW12O40 at 180 degrees C produces a material containing (Et3P)(2)PtH+ and (Et3P)(3)Pt-2-(mu-PEt2)(mu-H)Et+. Although the crystals lack permanent channels, exposure to (CH3CN)-C-13 vapor leads to extensive isotopic exchange. This is proposed to result from chemical microporosity of the solid.

  DOI：

  10.1016/s0020-1693(97)05507-2