Ru(2,2'-bipyridine)2(maleonitriledithiolate) | 118831-65-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ru(2,2'-bipyridine)2(maleonitriledithiolate)
• 英文别名: (Z)-1,2-dicyanoethene-1,2-dithiolate;2-pyridin-2-ylpyridine;ruthenium(2+)
• CAS: 118831-65-5
• 化学式: C₂₄H₁₆N₆RuS₂
• 分子量: 553.633
• InChiKey: MEBQKVZPKMYQFE-DVACKJPTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(2,2'-bipyridine)2(maleonitriledithiolate) 在 I₂ 作用下， 以 not given 为溶剂， 生成 bis(2,2'-bipyridine)(maleonitriledithiolate)Ru(III)(1+)
  参考文献：
  名称：

  Greaney; Coyle; Harmer, Inorganic Chemistry, 1989, vol. 28, # 5, p. 912 - 920

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(2,2'-bipyridine)(maleonitriledithiolate)Ru(III)(1+) 在 benzenethiol 作用下， 以 not given 为溶剂， 生成 Ru(2,2'-bipyridine)2(maleonitriledithiolate)
  参考文献：
  名称：

  Greaney; Coyle; Harmer, Inorganic Chemistry, 1989, vol. 28, # 5, p. 912 - 920

  摘要：

  DOI：

文献信息

• Prasad, R.; Prasad, S.; Agrwala, U. C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 1493 - 1506
  作者：Prasad, R.、Prasad, S.、Agrwala, U. C.

  DOI：——

  日期：——
• Mono- and dinuclear maleonitriledithiolate and dibenzyldithiomaleonitrile complexes of (bipy)2RuII: Synthesis, spectral and electrochemical study
  作者：Rajendra Prasad

  DOI：10.1016/0277-5387(95)00008-g

  日期：1995.8

  [Ru(bipy)(2)S2C2(CN)(2)}] and [Ru(bipy)(2)(C6H5CH2)(2)S2C2(CN)(2)}][PF6](2) were synthesized by the reaction of [Ru(bipy)(2)Cl-2] . 2H(2)O with Na2S2C2(CN)(2) or (C6H5CH2)(2) S2C2(CN)(2) in aqueous ethanol, and used to form dinuclear species by binding Cp(PPh(3))(2)Ru-II or (bipy)(2)ClRuII moieties onto the CN nitrogen sites. Spectral and electrochemical properties of all complexes have been investigated. S2C2(CN)(2)(2-) is found to introduce a low lying d pi(Ru) --> pi*(S2C2(CN)(2)(2-)) MLCT state and an easily oxidizable centre upon complexation. (C6H5CH2)(2)S2C2(CN)(2) exhibits weaker pi acidity and imparts a 2852 cm(-1), 0.35 V lower stabilization to the ruthenium d pi orbitals than the saturated chain dithioether (CH3)(2)S2C2H2, as indicated in the Ru --> bipy MLCT absorption energy and the first oxidation potential of the corresponding (bipy)(2)Ru-II complexes.