{Au(I)(pyridine-2-thionate)(triphenylphosphine)} | 132461-10-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {Au(I)(pyridine-2-thionate)(triphenylphosphine)}
• 英文别名: (pyridine-2-thiolato)Au(P(C6H5)3)
• CAS: 132461-10-0
• 化学式: C₂₃H₁₉AuNPS
• 分子量: 569.417
• InChiKey: QMKXTQRURRCKDL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.08
• 重原子数：
  27.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.89
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  pentafluorophenyl(tetrahydrothiophene)gold(I) 、 {Au(I)(pyridine-2-thionate)(triphenylphosphine)} 以 二氯甲烷 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  Uson, Rafael; Laguna, Antonio; Laguna, Mariano, Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：
• 作为产物：
  描述：

  {Au(pyridine-2-thione)(triphenylphosphine)}(ClO4) 在 Na₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 以43%的产率得到{Au(I)(pyridine-2-thionate)(triphenylphosphine)}
  参考文献：
  名称：

  Uson, Rafael; Laguna, Antonio; Laguna, Mariano, Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：

文献信息

• Synthesis and Structural Characterization of Gold(I) and Silver(I) Complexes of the Multidonor Ligand 2-(Phenacylthio)pyridine − Crystal Structures of [(AuPPh3){py{SCH2C(O)Ph}-2}](ClO4) and [(AgPPh3)(OClO3){py{SCH2C(O)Ph}-2}]
  作者：José Vicente、Maria-Teresa Chicote、Sonia Huertas、M. Carmen Ramírez de Arellano、Peter G. Jones

  DOI：10.1002/(sici)1099-0682(199804)1998:4<511::aid-ejic511>3.0.co;2-0

  日期：1998.4

  The ligand properties of 2-(phenacylthio)pyridine towards gold(I) and silver(I) have been investigated. From the reactions of the ligand with acetone solutions of [M(PPh3)(acetone)]ClO4 (M = Ag, Au) under various experimental conditions, complexes [(AuPPh3)npySCH2C(O)Ph}-2}](ClO)n, and [(AgPPh3)n(OClO3)npySCH2C(O)Ph}-2}](n = 1−3) have been obtained. The crystal structures of the complexes [(Au

  已经研究了 2-(phenacylthio) 吡啶对金 (I) 和银 (I) 的配体性质。从配体与 [M(PPh3)(丙酮)]ClO4 (M = Ag, Au) 的丙酮溶液在各种实验条件下的反应中，复合物 [(AuPPh3)npySCH2C(O)Ph}-2} ](ClO)n 和 [(AgPPh3)n(OClO3)npySCH2C(O)Ph}-2}](n = 1−3)。配合物[(AuPPh3)pySCH2C(O)Ph}-2}]ClO4和[(AgPPh3)(OClO3)pySCH2C(O)Ph}-2}]的晶体结构由X确定-射线衍射。在阳离子金络合物中，金属与氮和磷线性配位，而相应的银络合物则显示出带有吡啶、磷烷和高氯合配体的三角形平面几何形状。
• Triorganophosphinegold(I) complexes of pyridine-2-thionate and pyrimidine-2-thionate
  作者：Peter D. Cookson、Edward R. T. Tiekink

  DOI：10.1039/dt9930000259

  日期：——

  Triorganophosphinegold(I) complexes of the anions derived from pyridine-2-thione (2-pySH) and 1H-pyrimidine-2-thione (2-pymSH), [Au(PR3)(SR')] (R = Et, Ph or C6H11), have been prepared and characterized by spectroscopic (IR, H-1 and C-13 NMR and fast atom bombardment MS) methods and for the PPh3 compounds by X-ray crystallographic techniques. The mononuclear compounds feature linear gold atom geometries defined by P and S atoms with important parameters for [Au(PPh3)(2-pyS)]: Au-P 2.258(1), Au-S 2.297(2) angstrom and P-Au-S 177.9(1)degrees and for [Au(PPh3)(2-pymS)]: Au-P 2.253(2), Au-S 2.310(3) angstrom and P-Au-S 174.7(1)degrees. The [Au(PPh3)(2-pyS)] complex 2 crystallizes in the monoclinic space group P2(1)/c with unit-cell dimensions a = 12.235(1), b = 10.009(2), c = 1 7.292(2) angstrom, beta = 104.08(1)degrees and Z = 4; [Au(PPh3)(2-pymS)] 5 crystallizes in the triclinic space group P1BAR with a = 11.006(2), b = 11.356(4), c = 8.873(1) angstrom, alpha = 109.85(2), beta = 95.72(1), gamma = 93.55(2)degrees and Z = 2. The structures were refined to final R = 0.025 for 2527 reflections with I greater-than-or-equal-to 2.5sigma(I) and R = 0.057 for 3416 reflections with I greater-than-or-equal-to 2.5sigma(I) for 2 and 5, respectively.
• Bonati, Flavio; Burini, Alfredo; Pietroni, Bianca Rosa, Gazzetta Chimica Italiana, 1993, vol. 123, # 12, p. 691 - 696
  作者：Bonati, Flavio、Burini, Alfredo、Pietroni, Bianca Rosa、Galassi, Rossana

  DOI：——

  日期：——