bis(triphenylphosphine)(N-methyl-N-ethanoldithiocarbamato)nickel(II) perchlorate | 189205-07-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(triphenylphosphine)(N-methyl-N-ethanoldithiocarbamato)nickel(II) perchlorate
• 英文别名: [Ni(nmedtc)(PPh3)2]ClO4；Ni(N-methyl,N-ethanoldithiocarbamate)(PPh3)2ClO4；[Ni(N-(2-hydroxyethyl)-N-methyldithiocarbamate)(PPh3)2]ClO4
• CAS: 189205-07-0
• 化学式: C₄₀H₃₈NNiOP₂S₂*ClO₄
• 分子量: 832.968
• InChiKey: CABFWQDXCOXLTK-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  三苯基膦 、 sodium perchlorate 、 nickel(II) chloride hexahydrate 、 bis(N-methyl-N-ethanoldithiocarbamato)nickel(II) 以 甲醇 、 二氯甲烷 为溶剂， 以70%的产率得到bis(triphenylphosphine)(N-methyl-N-ethanoldithiocarbamato)nickel(II) perchlorate
  参考文献：
  名称：

  Synthesis and crystal structure of NiII complexes containing the NiS2P2 chromophore

  摘要：

  The nickel(II) complexes [Ni(nmedtc)(PPh(3))(2)]ClO4 (1) and [Ni(nmedtc)dppe]BPh(4) . CH2Cl2 (2) [nmedtc = N-methyl,N-ethanoldithiocarbamate, dppe = 1,2-bis(diphenylphosphino)ethane] were prepared and characterized by electronic and IR spectra, and their structures determined by X-ray crystallography. In both complexes the NiS2P2 chromophore is planar and the thioureide C-N has double bond character. Hydrogen bond interaction is observed in 1 between the ethanolic group and the perchlorate anion. Electronic and IR spectra confirm the planarity of the chromophores in both complexes and the contribution of the thioureide form in the molecular structure. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00532-3