2-Tert-butylphosphanylethanamine | 112150-09-1

• 分子结构分类: 有机化合物 - 有机卤素化合物
• 英文名称: 2-Tert-butylphosphanylethanamine
• CAS: 112150-09-1
• 化学式: C₆H₁₆NP
• 分子量: 133.173
• InChiKey: MUNMJWXPZXWPHY-UHFFFAOYSA-N

物化性质

• 沸点：
  183.2±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲基乙酰亚胺酯盐酸盐 、 2-Tert-butylphosphanylethanamine 在 sodium hydroxide 作用下， 生成 3-tert-butyl-2-methyl-4,5-dihydro-1,3-azaphosphole
  参考文献：
  名称：

  1H-1,3-azaphosphole - neue phosphaaromaten

  摘要：

  DOI：

  10.1016/s0040-4039(00)85304-6

文献信息

• POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE ASSEMBLY AND SOLID POLYMER FUEL CELL EACH USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20140377686A1

  公开（公告）日：2014-12-25

  Provided are: a practically excellent polymer electrolyte composition having excellent chemical stability of being resistant to strong oxidizing atmosphere during operation of fuel cell, and achieving excellent proton conductivity under low-humidification conditions, excellent mechanical strength and physical durability; a polymer electrolyte membrane, a membrane electrode assembly, and a polymer electrolyte fuel cell each using the same. The polymer electrolyte composition of the present invention comprises at least an ionic group-containing polymer (A) and a phosphorus-containing additive (B), the phosphorus-containing additive (B) being at least one of a phosphine compound and a phosphinite compound. The polymer electrolyte membrane, the membrane electrode assembly, and the polymer electrolyte fuel cell of the present invention are structured by the polymer electrolyte composition.

  提供了一种具有优异化学稳定性，在燃料电池操作期间对强氧化气氛具有抗性，并在低加湿条件下实现优异的质子传导性、优异的机械强度和物理耐久性的实用优良聚合物电解质组成物；以及使用相同组成物的聚合物电解质膜、膜电极组件和聚合物电解质燃料电池。本发明的聚合物电解质组成物包括至少一种离子基团含有的聚合物（A）和一种含磷添加剂（B），该含磷添加剂（B）至少为膦化合物和膦酸酯化合物中的一种。本发明的聚合物电解质膜、膜电极组件和聚合物电解质燃料电池由聚合物电解质组成物构成。
• Heinicke, Joachim; Tzschach, Alfred, Zeitschrift fur Chemie, 1986, vol. 26, # 11, p. 407 - 408
  作者：Heinicke, Joachim、Tzschach, Alfred

  DOI：——

  日期：——
• HEINICKE J.; TZSCHACH A., Z. CHEM., 26,(1986) N 11, 407-408
  作者：HEINICKE J.、 TZSCHACH A.

  DOI：——

  日期：——
• POLYMER ELECTROLYTE COMPOSITION AND POLYMER ELECTROLYTE MEMBRANE, POLYMER ELECTROLYTE MEMBRANE WITH CATALYST LAYER, MEMBRANE ELECTRODE ASSEMBLY, AND POLYMER ELECTROLYTE FUEL CELL EACH USING THE SAME
  申请人：Toray Industries, Inc.

  公开号：US20170033387A1

  公开（公告）日：2017-02-02

  An excellent polymer electrolyte composition has excellent chemical stability of being resistant to strong oxidizing atmosphere during operation of fuel cell, and achieves excellent proton conductivity under low-humidification conditions, excellent mechanical strength and physical durability. A polymer electrolyte membrane, a membrane electrode assembly, and a polymer electrolyte fuel cell each use the same. The polymer electrolyte composition contains an ionic group-containing polymer (A), a phosphorus-containing additive (B), and a nitrogen-containing aromatic additive (C), the phosphorus-containing additive (B) and the nitrogen-containing aromatic additive (C) being a compound represented by specific structural formulae.
• US9685674B2
  申请人：——

  公开号：US9685674B2

  公开（公告）日：2017-06-20