bis(tetramethyldithioimidodiphosphinato)cobalt(II) | 31747-72-5

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: bis(tetramethyldithioimidodiphosphinato)cobalt(II)
• CAS: 31747-72-5
• 化学式: C₈H₂₄CoN₂P₄S₄
• 分子量: 459.444
• InChiKey: VTUFGTZESMRLGL-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 Potassium;bis[dimethyl(sulfido)phosphaniumyl]azanide 以 甲醇 为溶剂， 以75%的产率得到bis(tetramethyldithioimidodiphosphinato)cobalt(II)
  参考文献：
  名称：

  Crystal and Molecular Structure of Tetramethyldithioimidodiphosphinic acid, (SPMe2)2NH, and Its Cobalt(II) Complex, Co[(SPMe2)2N]2, Containing a Tetrahedral CoS4 Core

  摘要：

  The crystal and molecular structure of (SPMe(2))(2)NH and its cobalt(II) complex were determined by X-ray diffraction. In the crystal the molecules of the free acid are associated into polymeric chains through N(1)-H(1')...S(2a) hydrogen bonds, which results in the non-equivalence of the P=S bond lengths (P(1)-S(1) = 1.939(2), and P(2)-S(2) = 1.962(2) Angstrom) within the molecular unit. The crystal of Co[(SPMe(2))(2)N](2) contains discrete monomeric molecules, exhibiting a spirobicyclic system with a slightly distorted tetrahedral CoS4 core.

  DOI：

  10.1021/ic00116a030