9,9-dibutylfluorene-3-methanol | 1246026-62-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9,9-dibutylfluorene-3-methanol
• 英文别名: (9,9-Dibutylfluoren-3-yl)methanol；(9,9-dibutylfluoren-3-yl)methanol
• CAS: 1246026-62-9
• 化学式: C₂₂H₂₈O
• 分子量: 308.464
• InChiKey: UEHNVVBTLUFOIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,9-dibutylfluorene-3-methanol 在 氢溴酸 作用下， 反应 4.0h， 以96%的产率得到3-bromomethyl-9,9-dibutylfluorene
  参考文献：
  名称：

  Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues

  摘要：

  Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.064
• 作为产物：
  描述：

  9,9-dibutylfluorene-3-carbaldehyde 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 以90.4%的产率得到9,9-dibutylfluorene-3-methanol
  参考文献：
  名称：

  Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues

  摘要：

  Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.064

文献信息

• Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues
  作者：Yabin Song、Wei Xu、Daoben Zhu

  DOI：10.1016/j.tetlet.2010.07.064

  日期：2010.9

  Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.