5,10-dihydrobenzo[f]thieno[3,4-b][1,4]dioxocine | 202927-43-3

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 5,10-dihydrobenzo[f]thieno[3,4-b][1,4]dioxocine
• 英文别名: 5,10-Dihydrothieno[3,4-c][2,5]benzodioxocine
• CAS: 202927-43-3
• 化学式: C₁₂H₁₀O₂S
• 分子量: 218.276
• InChiKey: WYKOFXPUWYOSTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  46.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5,10-dihydrobenzo[f]thieno[3,4-b][1,4]dioxocine-1,3-dicarboxylic acid 在 喹啉 、 copper chromite 作用下， 反应 8.0h， 以50%的产率得到5,10-dihydrobenzo[f]thieno[3,4-b][1,4]dioxocine
  参考文献：
  名称：

  Preparation of an EDOT-based polymer: optoelectronic properties and electrochromic device application

  摘要：

  一个新型TPA/DTD电致变色器件的光谱电化学图。

  DOI：

  10.1039/c4ra13060j

文献信息

• Process for making biosensor
  申请人：NovioSense B.V.

  公开号：EP2653868A1

  公开（公告）日：2013-10-23

  A process for making a biosensor comprising a hollow coil comprising wires coiled in parallel and an electronic circuit component connected to the coil, the process comprising: 1) providing a mandrel on which wires including at least a first wire, a second wire and a third wire are wound in parallel, 2a) immersing the mandrel in a first buffer solution comprising a first bioreceptor, a first monomer and optional additives, 2b) arranging the wires such that the first wire may be used as a working electrode, the second wire may be used as a counter electrode and the third wire may be used as a reference electrode of a three electrode electrochemical cell used in an electropolymerisation process, 3) passing electric current through the first wire to form a first biocompatible coating of a first polymer polymerized from the first monomer comprising the first bioreceptor on the first wire, 4) removing the coil from the mandrel, 5) connecting the wires to their respective points of the electronic circuit component such that the first wire may be used as a working electrode, the second wire may be used as a counter electrode and the third wire may be used as a reference electrode and wherein the electronic circuit component is configured such that it can generate an input signal for a wireless receiver based upon the activity of the bioreceptor and wirelessly send the input signal to the wireless receiver.

  一种制造生物传感器的工艺，该传感器包括一个由平行卷绕的导线组成的空心线圈和一个连接到线圈上的电子电路元件，该工艺包括：1）提供一个心轴，在心轴上平行卷绕至少包括第一根导线、第二根导线和第三根导线在内的导线；2a）将心轴浸入包含第一种生物受体、第一种单体和可选添加剂的第一缓冲溶液中；2b）排列导线，使第一根导线可用作工作电极，第二根导线可用作对电极，第三根导线可用作电聚合过程中使用的三电极电化学电池的参比电极、3) 将电流通过第一导线，以在第一导线上形成由包含第一生物受体的第一单体聚合而成的第一聚合物的第一生物相容性涂层， 4) 将线圈从心轴上取下， 5) 将导线连接到电子电路组件的各自点上，以便将第一导线用作工作电极、第二根导线可用作对电极，第三根导线可用作参比电极，其中，电子电路组件的配置使其能够根据生物受体的活动为无线接收器生成输入信号，并以无线方式将输入信号发送到无线接收器。
• Diprotodecarboxylation Reactions of 3,4-Dialkoxythiophene-2,5-dicarboxylic Acids Mediated by Ag₂CO₃ and Microwaves
  作者：Pablo A. Cisneros-Pérez、Diego Martínez-Otero、Erick Cuevas-Yánez、Bernardo A. Uribe-Frontana

  DOI：10.1080/00397911.2013.800212

  日期：2014.1.17

  An efficient and rapid method is reported to obtain 3,4-dialkoxythiophenes from 3,4-dialkoxythiophene-2,5-dicarboxylic acids through a diprotodecarboxylation reaction with Ag2CO3/AcOH as a catalytic system and microwave heating in dimethylsulfoxide (DMSO) as solvent. This methodology lets us obtain for the first time good performance with thiophenes bearing strong electron-donating groups such as alkoxides. This methodology eliminates the usage of harmful quinoline as solvent, as well as the long reaction times typically used (12-18h) to obtain the 3,4-dialkoxythiophenes. The reaction of 7 diacids showed good yields (60-89%) following 20min of microwave heating in a temperature range of 120-150 degrees C. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]
• Highly transparent electrochromic coating material, method for producing the same and use of the material
  申请人：Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.

  公开号：EP1928000B1

  公开（公告）日：2009-05-20
• ELECTROCHEMICAL BIOSENSOR BASED ON HOLLOW COILS
  申请人：NovioSense B.V.

  公开号：EP2699690A2

  公开（公告）日：2014-02-26
• PROCESS FOR MAKING BIOSENSOR
  申请人：NovioSense B.V.

  公开号：EP2839285A1

  公开（公告）日：2015-02-25