[Mn(4,4'-bipyridine)(trichloroacetato)2(H2O)] | 444571-78-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Mn(4,4'-bipyridine)(trichloroacetato)2(H2O)]
• CAS: 444571-78-2
• 化学式: C₁₄H₁₀Cl₆MnN₂O₅
• 分子量: 553.9
• InChiKey: CPRHJDJKCIIOKI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mn(4,4'-bipyridine)(trichloroacetato)2(H2O)] 以 neat (no solvent) 为溶剂， 生成 manganese oxide
  参考文献：
  名称：

  摘要：

  New mixed-ligand complexes of general formulae Mn(4-bpy)(CCl3COO)(2).H2O, Ni(4-bPY)(2)(CCl3COO)(2).2H(2)O and Zn(4-bpy)(2)(CCl3COO)2.2H(2)O (where 4-bpy=4,4'-bipyridine) were obtained and characterized. The IR spectra, conductivity measurements and other physical properties of these compounds were discussed. The central atoms M(IT) form coordinate bonds with title ligands. The thermal behaviour of the synthesized complexes was studied in air. During heating the complexes decompose via different intermediate products to Mn3O4, NiO and ZnO; partial volatilization of ZnCl2 was observed. A coupled TG-MS system was used to the analysis of the principal volatile thermal decomposition products of Mn(II) and Ni(II) complexes. The principal volatile mass fragments correspond to: H2O+, OH+, CO'(2), HCl+, Cl-2, CCl+ and other.

  DOI：

  10.1023/a:1014365007321
• 作为产物：
  描述：

  2,2'-联吡啶 、 manganese (II) trichloroacetate 、 水 以 乙醇 、 水 为溶剂， 生成 [Mn(4,4'-bipyridine)(trichloroacetato)2(H2O)]
  参考文献：
  名称：

  摘要：

  New mixed-ligand complexes of general formulae Mn(4-bpy)(CCl3COO)(2).H2O, Ni(4-bPY)(2)(CCl3COO)(2).2H(2)O and Zn(4-bpy)(2)(CCl3COO)2.2H(2)O (where 4-bpy=4,4'-bipyridine) were obtained and characterized. The IR spectra, conductivity measurements and other physical properties of these compounds were discussed. The central atoms M(IT) form coordinate bonds with title ligands. The thermal behaviour of the synthesized complexes was studied in air. During heating the complexes decompose via different intermediate products to Mn3O4, NiO and ZnO; partial volatilization of ZnCl2 was observed. A coupled TG-MS system was used to the analysis of the principal volatile thermal decomposition products of Mn(II) and Ni(II) complexes. The principal volatile mass fragments correspond to: H2O+, OH+, CO'(2), HCl+, Cl-2, CCl+ and other.

  DOI：

  10.1023/a:1014365007321